APPLICATION OF CROSS-LINKED CHITOSAN FOR PHOSPHATE REMOVAL FROM AQUEOUS SOLUTIONS

• Authors: Urszula Filipkowska , Tomasz Jóźwiak , Paula Szymczyk
• Languages of publication: EN EN

Abstracts

EN

This study investigated the effectiveness of phosphate adsorption onto non-cross-linked chitosan beads [CHs], and onto chitosan beads cross-linked with glutaraldehyde [ALD-CHs] and epichlorohydrin [ECH-CHs]. The weight ratio of glutaraldehyde to chitosan was 1:2 (w/w), whereas that of epichlorohydrin to chitosan was 2:1 (w/w). The optimal pH value of the phosphate adsorption process was determined at pH 3 for cross-linked chitosan and at pH 4 for noncross- linked chitosan. The time needed to reach the equilibrium concentration reached 60 min for both adsorbents. Experimental data were described with the heterogeneous Langmuir model (double Langmuir equation). The most effective adsorbent of phosphates was shown to be chitosan cross-linked with epichlorohydrin [ECH-CHs] - for which the adsorption capacity reached 139.4 mg/g d.m.CHs. In the case of the remaining adsorbents (chitosan [CHs] and chitosan crosslinked with glutaraldehyde [ALD-CHs]) the adsorption capacity was lower and accounted for 44.38 mg/g d.m.CHs and 108.24 mg/g d.m.CHs, respectively.

Keywords

EN

adsorption; chitosan; cross-linked chitosan; epichlorohydrin; glutaraldehyde; phosphates

Discipline

• ENVIRONMENT_&_ECOLOGY: ENVIRONMENT & ECOLOGY

• Publisher: Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
• Journal: Progress on Chemistry and Application of Chitin and its Derivatives
• Year: 2014
• Volume: 19
• Pages: 5-14

Contributors

author

Urszula Filipkowska

• Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn

author

Tomasz Jóźwiak

• Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn

author

Paula Szymczyk

• Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn

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• Document Type: article