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2019 | 27 | 22-37
Article title

Adsorption behavior of pharmaceutically active dexketoprofen as sustainable corrosion Inhibitor for API X80 carbon steel in acidic medium

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The inhibition of X80 carbon steel corrosion in 1 M HCl solution by dexketoprofen (DKP) was studied using weight loss (WL), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP) and scanning electron microscopy (SEM) techniques. The results indicated that DKP acts by way of adsorption as an effective protective inhibitor in the aggressive acid medium. The inhibition efficiency of DKP increased with concentration but was lower at higher temperature. The results of potentiodynamic polarization showed that DKP molecule behaved as a mixed type inhibitor by reducing both the anodic and the cathodic electrochemical reactions. Dexketoprofen was adsorbed on the X80 steel surface in accordance with Langmuir adsorption isotherm. SEM analyses supported formation of protective film on the X80 steel in the presence of DKP.
Physical description
  • Electrochemistry and Material Science Unit, Department of Chemistry, Federal University, Otuoke, P.M.B 126, Yenagoa, Bayelsa, Nigeria
  • Department of Pure and Industrial Chemistry, University of Port Harcourt, Port Harcourt, Nigeria
  • [1] H. F. El-Shamy, Y. A. Aggour, A. M. Ahmed, Study the metallic finishing and corrosion control processes for carbon steel overhead pipes using polymer molecules. MOJ Biorg Org Chem 1(5) (2017) 1-11
  • [2] K. Zhang, B. Xu, W. Yang, X. Yin, Y. Liu, Y. Chen, Halogen-substituted imidazoline derivatives as corrosion inhibitors for mild steel in hydrochloric acid solution. Corros. Sci. 90 (2015) 284-295.
  • [3] X. Zheng, S. Zhang, W. Li, L. Yin, J. He, J. Wu, Investigation of 1-butyl-3-methyl-1H-benzimidazolium iodide as inhibitor for mild steel in sulfuric acid solution. Corros Sci. 80 (2014) 383-392
  • [4] A. Alobaidy, A. Kadhum, S. Al-Baghdadi, A. A. Al-Amiery, E. Yousif, A. Mohamad, Eco-Friendly Corrosion Inhibitor: Experimental Studies on the Corrosion Inhibition Performance of Creatinine for Mild Steel in HCl Complemented with Quantum Chemical Calculations. Int. J. Electrochem. Sci. 10 (2015) 3961-3972
  • [5] E. Yousif, Y. Win, A. H. Al-Hamadani, A. A. Al-Amiery, A. Mohamad, Furosemide as an Environmental-Friendly Inhibitor of Corrosion of Zinc metal in Acid Medium: Experimental and Theoretical studies. Int. J. Electrochem. Sci. 10 (2015) 1708-1715
  • [6] N. B. Iroha, E. E. Oguzie, G. N. Onuoha and A. I. Onuchukwu, Inhibition of Mild Steel Corrosion in Acidic Solution by derivatives of Diphenyl Glyoxal. 16th International Corrosion Congress, Beijing, China, (20051) 26-131
  • [7] H. Ashassi-Sorkhabi, B. Shaabani, D. Seifzadeh, Effect of Some Pyrimidinic Shciff Bases on the Corrosion of Mild Steel in Hydrochloric Acid Solution. Electrochim. Acta 50 (2005) 3446-3452
  • [8] N. O. Eddy, S. A. Odoemelam, A. O. Odiongenyi, Joint effect of halides and ethanol extract of Lasianthera africana on inhibition of corrosion of mild steel in H2SO4. J. Appl. Electrochem. 39 (2009) 849-857
  • [9] A. Barbosa da Silva, E. D'Elia, J. A. C. P. Gomes, Carbon steel corrosion inhibition in hydrochloric acid solution using a reduced Schiff base of ethylenediamine. Corros. Sci. 52 (2010) 788-793
  • [10] C. Verma, M. A. Quraishi, A. Singh, 5-Substituted 1H-tetrazoles as effective corrosion inhibitors for mild steel in 1 M hydrochloric acid. J. Taibah Uni. Sci. 10 (2016) 718-733
  • [11] I. B. Obot, N. O. Obi-Egbedi, S. A. Umoren, Adsorption characteristics and corrosion inhibitive properties of clotrimazole for aluminium corrosion in hydrochloric acid. International Journal of Electrochemical Science 4 (2009) 863- 877
  • [12] M. Abdallah, Rhodanine azosulpha drugs as corrosion inhibitors for corrosion of 304 stainless steel in hydrochloric acid solution. Corrosion Science 44 (2002) 717-728
  • [13] N. O. Eddy, S. A. Odoemelam, Norfloxacin and Sparfloxacin as corrosion inhibitors for zinc. Effect of concentrations and temperature. Journal of Materials Science 4 (2008) 87-96
  • [14] A. S. Mahdi, Amoxicillin as green corrosion inhibitor for concrete reinforced steel in simulated concrete pore solution containing chloride. International Journal of Advanced Research in Engineering and Technology 5 (2014) 99-107
  • [15] E. E. Ebenso, N. O. Eddy, A. O. Odiongenyi, Corrosion inhibition and adsorption properties of methocarbamol in mild steel in acidic medium. Portugaliae Electrochimica Acta 27 (2009) 13-22
  • [16] I. A. Akpan, N. O. Offiong, Electrochemical study of corrosion inhibition action of sulphadoxine and pyrimethamine on mild steel in acidic medium. International Journal of Chemical and Process Engineering Research 1 (2014) 10-18
  • [17] S. Mani megalai, R. Ramesh, P. Manjula, Inhibition of corrosion mild steel in acid media by Trazodone drug. Research Desk 2 (2013) 326-333
  • [18] A. S. Fouda, S. M. Rashwan, M. M. Kamel, A. Ibrahim, Tenormin drug as save corrosion inhibitor for 304 stainless steel in hydrochloric acid solutions. Der Pharma Chemica 7 (2015) 22-33
  • [19] P. M. Nouri, M. M.Attar, Experimental and quantum chemical studies on corrosion inhibition performance of Fluconazole in hydrochloric acid solution. Bulletin of Materials Science 38 (2015) 499-509
  • [20] K. R. Ansari, M. A. Quraishi, E.E. Ebenso, Electrochemical and thermodynamic investigation of Diclofenac sodium drug as a potential corrosion inhibitor for mild steel in hydrochloric acid. International Journal of Electrochemical Science 8 (2013) 12860-12873
  • [21] N. B. Iroha and A. Hamilton-Amachree, Adsorption and anticorrosion performance of Ocimum Canum extract on mild steel in sulphuric acid pickling environment. American Journal of Materials Science 8(2) (2018) 39-44.
  • [22] N. A. Madueke and N. B. Iroha, Protecting aluminium alloy of type AA8011 from acid corrosion using extract from Allamanda cathartica leaves. International Journal of Innovative Research in Science, Engineering and Technology 7(10) (2018) 10251-10258
  • [23] O. James and E. O. Ekpe, Inhibition of corrosion of mild steel in 2M hydrochloric acid by Aloe Vera. International Journal of Pure and Applied Chemistry 35(10) (2002)
  • [24] J. N. O. Ezeugo, O. D. Onukwuli, M. Omotioma. Optimization of corrosion inhibition of Picralima nitida leaves extract as green corrosion inhibitor for zinc in 1.0 M HCl. World News of Natural Sciences 15 (2017) 139-161
  • [25] N. B. Iroha and A. O. James, Assessment of performance of velvet tamarind-furfural resin as corrosion inhibitor for mild steel in acidic solution. J. Chem Soc. Nigeria 43(3) (2018) 510-517
  • [26] H. Louis, J. Japari, A. Sadia, M. Philip, A. Bamanga. Photochemical screening and corrosion inhibition of Poupartia birrea back extracts as a potential green inhibitor for mild steel in 0.5 M H2SO4 medium. World News of Natural Sciences 10 (2017) 95-100
  • [27] N. B. Iroha, O. Akaranta and A. O. James, Corrosion Inhibition of Mild Steel in Acid Media by Red Peanut skin extract-furfural Resin. Advances in Applied Science Research 3(6) (2012) 3593-3598
  • [28] S. A. Umoren, Y. Li, F. H. Wang, Electrochemical study of corrosion inhibition and adsorption behaviour for pure iron by polyacrylamide in H2SO4: Synergistic effect of iodide ions. Corros. Sci. 52 (2010) 1777-1786
  • [29] M. Scendo, J. Uznanska, The effect of ionic liquids on the corrosion inhibition of copper in acidic chloride solutions. Int J Corros (2011) 1-13
  • [30] N. B. Iroha, A. Hamilton-Amachree, Inhibition and adsorption of oil extract of Balanites aegyptiaca seeds on the corrosion of mild steel in hydrochloric acid environment. World Scientific News 126 (2019) 183-197.
  • [31] A. O. James and N. B. Iroha, An Investigation on the Inhibitory Action of Modified Almond Extract on the Corrosion of Q235 Mild Steel in Acid Environment, IOSR Journal of Applied Chemistry 12(2) (2019) 01-10
  • [32] E. S. Ferreira, C. Giancomelli, F. C. Giacomelli, A. Spinelli, Evaluation of the inhibitor effect of l-ascorbic acid on the corrosion of mild steel. Mater. Chem. Phys. 83 (2004) 129-134
  • [33] H. A. Sorkhabi, M. R. Majidi, K. Seyyedi, Investigation of inhibition effect of some amino acids against steel corrosion in HCl solution. Appl. Surf. Sci. 225 (2004) 176-185
  • [34] [34] M. A. Chidiebere, N. Simeon, D. Njoku, N. B. Iroha, E. E. Oguzie and Y. Li, Experimental study on the inhibitive effect of phytic acid as a corrosion inhibitor for Q235 mild steel in 1 M HCl environment. World News of Natural Sciences 15 (2017) 1-19
  • [35] L. O. Olasunkanmi, M. M. Kabanda, E. E. Ebenso, Quinoxaline derivatives as corrosion inhibitors for mild steel in hydrochloric acid medium: Electrochemical and quantum chemical studies. Physica E 76 (2016) 109-126
  • [36] A. Bouyanzer, B. Hammouti, L. Majidi, Pennyroyal oil from Mentha pulegium as corrosion inhibitor for steel in 1 M HCl. Materials Letters 60(23) (2006) 2840-2843
  • [37] N. B. Iroha and M. A. Chidiebere, Evaluation of the Inhibitive Effect of Annona Muricata. L Leaves Extract on Low-Carbon Steel Corrosion in Acidic Media. International Journal of Materials and Chemistry 7(3) (2017) 47-54
  • [38] C. Verma, L. O. Olasunkanmi, E. E. Ebenso, M. A. Quraishi, I. B. Obot, Adsorption behavior of glucosamine-based, pyrimidine-fused heterocycles as green corrosion inhibitors for mild steel: experimental and theoretical studies. J. Phys. Chem. C 120 (2016) 11598-11611.
  • [39] Z. Z. Tong, J. Q. Xue, R. Y. Wang, J. Huang, J. T. Xu, Z. Q. Fan, Hierarchical self-assembly, photo-responsive phase behavior and variable tensile property of azobenzene-containing ABA triblock copolymers. RSC Adv. 5 (2015) 4030-4040
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