PL EN


Preferences help
enabled [disable] Abstract
Number of results
2020 | 31 | 120-137
Article title

Seed Shells as Active and Nontoxic Corrosion Inhibitors for Aluminum in Aggressive Acid Environment

Content
Title variants
Languages of publication
EN
Abstracts
EN
Chemical (weight loss and thermometric) measurements were used to study the corrosion inhibition characteristics of five seed shells, namely Afzelia africana seed shell (AASS), Brachystegia eurycoma seed shell (BESS), Derium microcarpum seed shell (DMSS), Mucuna flagellipes seed shell (MFSS) and Pentaclethra macrophlla seed shell (PMSS), respectively, on the inhibition of aluminum corrosion in aggressive 2.0 % HCl solutions at 30 and 50 °C for 8 hrs. Weight loss and thermometric measurements demonstrated that the seed shells (AASS, BESS, DMSS, MFSS and PMSS extracts) act as good corrosion inhibitors. Addition of the seed shell extracts decreases the corrosion rate of the process thereby improving inhibition performance. The result also reveals that the five seed shell extracts adsorb on the Aluminum surface through physical adsorption in accordance with Flory-Huggins and Langmuir adsorption isotherms at all temperatures investigated. Kinetic-thermodynamic parameters indicate a spontaneous adsorption process. Results of inhibition efficiency demonstrates that DMSS extract performed better as compared to BESS, AASS, PMSS and MFSS extracts.
Year
Volume
31
Pages
120-137
Physical description
Contributors
  • Department of Chemical Engineering, Nnamdi Azikiwe University, Awka, Nigeria
  • Department of Chemical Engineering, Nnamdi Azikiwe University, Awka, Nigeria
  • Department of Chemical Engineering, Nnamdi Azikiwe University, Awka, Nigeria
References
  • [1] M. Acharya. J. Singh Chouhan, A. Dixit, D. K. Gupta, Green Inhibitors for Prevention of Metal and Alloys Corrosion: An Overview. Chemistry and Materials Research, 3(6) (2013) 16-24
  • [2] M. Atta Ayman, A. El-Mahdy Gamal, A. Al-Lohedan Hamad and A. Al-Hussain Sami, Corrosion Inhibition of Mild Steel in Acidic Medium by Magnetite Myrrh Nanocomposite. Int. J. Electrochem. Sci. 9 (2014) 8446-8457
  • [3] P.M. Ejikeme, S.G. Umana and O.D. Onukwuli, corrosion inhibition of Aluminum by Treculia africana leaves extract in acid medium. Portugaliae Electrochemical Acta 30(5) (2012) 317-328. DOI: 10.4152/pea201205317
  • [4] I.B. Obot, N.O. Obi-Egbedi, Ginseng Root: A new Efficient and Effective Eco-Friendly Corrosion Inhibitor for Aluminium Alloy of type AA 1060 in Hydrochloric Acid Solution. Int. J. Electrochem. Sci. 4 (2009) 1277-1288
  • [5] Ating, E.I., Umoren, S.A., Udousoro, I.I., Ebenso, E.E., and Udoh, A.P., Leaves extract of Ananas sativum as a green corrosion inhibitor for aluminum in hydrochloric acid solutions. Green Chemistry Letters and Reviews, 3(2) (2010) 61-68
  • [6] Khaled K.F., Electrochemical investigation and modeling of corrosion inhibition of aluminum in molar nitric acid using some sulphur-containing amines. Corrosion Science 52 (2010) 2905-2916
  • [7] Chetouani A., Hammouti B. and Benkaddour M., (2004), Corrosion inhibition of iron in hydrochloric acid solution by jojoba oil. Pigment & Resin Technology, 33(1) 26-31. DOI: 10.1108/03699420410512077
  • [8] Pandian Bothi Raja, Ahmad Kaleem Qureshi, Afidah Abdul Rahim, Hasnah Osman, Khalijah Awang, Neolamarckia cadamba alkaloids as eco-friendly corrosion inhibitors for mild steel in 1 M HCl media. Corrosion Science, 69 (2013) 292-301
  • [9] Oguzie E.E., Enenebeaku C.K., Akalezi C.O., Okoro S.C., Ayuk A.A., Ejike E.N., Adsorption and corrosion-inhibiting effect of Dacryodis edulis extract on low-carbon-steel corrosion in acidic media. Journal of Colloid and Interface Science, 349 (2010) 283-292
  • [10] Emembolu L. N., Onukwuli O. D., Okafor V. N., Characterization and Optimization study of Epiphyllum oxypetalum extract as corrosion inhibitor for mild steel in 3 M H2SO4 solutions. World Scientific News 145 (2020b) 256-273
  • [11] Onukwuli Okechukwu Dominic, Anadebe Valentine Chikaodili and Okafor Chizoba Sandra, Optimum prediction for inhibition efficiency of Sapium ellipticum leaf extract as corrosion inhibitor of aluminum alloy (aa3003) in hydrochloric acid solution using electrochemical impedance spectroscopy and response surface, methodology. Bull. Chem. Soc. Ethiop. 34(1), 175-191. https://dx.doi.org/10.4314/bcse.v34i1.17
  • [12] Punita Mourya, Sitashree Banerjee, M.M. Singh, (2014), Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor. Corrosion Science, 85, 352-363
  • [13] Uwah I.E., Okafor P.C., Ebiekpe V.E., Inhibitive action of ethanol extracts from Nauclea latifolia on the corrosion of mild steel in H2SO4 solutions and their adsorption characteristics. Arabian Journal of Chemistry, 6 (2013) 285-293
  • [14] Subhadra Garai, Saraswati Garai, Parasuraman Jaisankar, J.K. Singh, Adirajan Elango, A comprehensive study on crude methanolic extract of Artemisia pallens (Asteraceae) and its active component as effective corrosion inhibitors of mild steel in acid solution. Corrosion Science, 60 (2012) 193-204
  • [15] Joseph NO Ezeugo, Optimization of corrosion inhibition of Picralima nitida seed extracts as a green corrosion inhibitor for zinc in 0.5 M H2SO4. International Journal of Chemical Studies, 6(4) (2018) 2080-2088
  • [16] Emembolu L. N., Onukwuli O. D. Effect of Dialium guineense extracts on the corrosion inhibition of aluminum in alkaline solutions. J. Mater. Environ. Sci. 10(6) (2019a) 495-509
  • [17] Loveth N. Emembolu, Dominic O. Onukwuli, Corrosion Inhibitive Efficacy of Natural Plant Extracts on Zinc in 0.5 M HCl Solution. The Pharmaceutical and Chemical Journal, 6(2) (2019b) 62-70
  • [18] Emembolu L. N., Igbokwe P.K., Inhibition capability of Dennettia tripetala leaves extract on low carbon steel in 4 M HCL solutions. Journal of Basic and Applied Research International, 24 (2020a) 23-35
  • [19] Al-Otaibi M.S., Al-Mayouf A.M., Khan M., Mousa A.A., Al-Mazroa S.A., Alkhathlan H.Z., Corrosion inhibitory action of some plant extracts on the corrosion of mild steel in acidic media. Arabian Journal of Chemistry, 7 (2014) 340-346
  • [20] Innocent Okechi Arukalam, Innocent Chimezie Madufor and Okoro Ogbobe, Emeka E. Oguzie, Hydroxypropyl methylcellulose as a polymeric corrosion inhibitor for aluminium. Pigment & Resin Technology, 43(3) (2014) 151-158
  • [21] Aoufir Y., Sebhaoui El J., Lgaz H., El Bakri Y., Zarrouk A., Bentiss F., Guenbour A., Essassi E.M., Oudda H., Corrosion inhibition of carbon steel in 1M HCl by 1,5-benzodiazepine derivative: Experimental and molecular modeling studies. Journal of Materials and Environmental Sciences 8(6) (2017) 2161-2173
  • [22] Rosemary I. Uchegbu, Lynda C. Ngozi – Olehi, Cliff N. Mbadiugha, Ahamefula A. Ahuchogu and Obiaku E. Ogbuagu (2015). Phytochemical evaluation by gc-ms analysis of the seeds of Mucuna flagellipes extract. Journal of Natural Sciences Research, 5(12): 103-109
  • [23] Olorunmaiye, KS; Apeh, LE; Madandola, HA; Oguntoye, MO, Proximate and Phytochemical Composition of African Mahogany (Afzelia africana) seed and African mesquite (Prosopis africana) pod. J. Appl. Sci. Environ. Manage 23(2) (2019) 249-252
  • [24] Ammar Ali, Sarah Falih, Nedal Yousif, Reben Rezgar, Ibtisam Kamal, Modeling and Optimization of Structural Steel Corrosion Inhibition using Barely Grass Extract as Green Inhibitor. American Journal of Environmental Engineering, 7(4) (2017) 73-81. DOI: 10.5923/j.ajee.20170704.01
  • [25] Ihebrodike, M.M., Nwandu, M.C., Okeoma, K.B., Nnanna, L.A., Chidiere, M.A., Eze, F.C., & Oguzie, E.E., Experimental and theoretical assessment of the inhibiting action of Aspilia africana extract on corrosion of Aluminum alloy AA 3003 in hydrochloric acid. J. Mat. Sci, 47 (2012) 2559-2572, DOI: 10.1007/s 10853-011-6079-2.S
  • [26] Aprael S. Yaro, Anees A. Khadom & Rafal K. Wael., Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid. Alexandria Engineering Journal (52) (2013) 129–135.
  • [27] Eddy N.O. & Ebenso E.E., Adsorption and inhibitive properties and of ethanol extract of Musa Sapientum peels as a green corrosion inhibitor for mild steel in H2SO4. Afri. J. Appl. Chem 2(6) (2008) 1-9
  • [28] Abel A. Negm, Nadia G. Kandle, Emad A. Badr, Mohammed A. Mohammed. Gravimetric and electrochemical evaluation of environmentally friendly nonionic corrosion inhibitors for carbon steel in 1 M HCl. Corrosion Science 65 (2012) 94-103
  • [29] Iroha N. B., Nnanna L. A., Electrochemical and Adsorption Study of the anticorrosion behavior of Cefepime on Pipeline steel surface in acidic Solution. J. Mater. Environ. Sci. 10(10) (2019) 898-908
  • [30] Tsoeunyane M. G., Makhatha M. E., and Arotiba O. A., Corrosion Inhibition of Mild Steel by Poly(butylene succinate)-L-histidine Extended with 1,6-diisocynatohexane Polymer Composite in 1 M HCl. International Journal of Corrosion, (2019) Article ID 7406409. https://doi.org/10.1155/2019/7406409
  • [31] Xia Wang, Huan Jiang, Dai-xiong Zhang, Li Hou, Wen-jie Zhou, Solanum lasiocarpum L. Extract as Green Corrosion Inhibitor for A3 Steel in 1 M HCl Solution. Int. J. Electrochem. Sci. 14 (2019) 1178-1196. doi:10.20964/2019.02.06
  • [32] Mohammad Mobin, Marziya Rizvi, Lukman O. Olasunkanmi, and Eno E. Ebenso, Biopolymer from Tragacanth Gum as a Green Corrosion Inhibitor for Carbon Steel in 1 M HCl Solution. ACS Omega 2 (2017) 3997-4008. DOI:10.1021/acsomega.7b00436
  • [33] L. N. Emembolu, O. D. Onukwuli, V. N. Okafor, Characterization and optimization study of Epiphyllum oxypetalum extract as corrosion inhibitor for mild steel in 3 M H2SO4 solutions. World Scientific News 145 (2020) 256-273
  • [34] Maduabuchi A. Chidiebere, Simeon Nwanonenyi, Demian Njoku, Nkem B. Iroha, Emeka E. Oguzie, Ying Li. Experimental study on the inhibitive effect of phytic acid as a corrosion inhibitor for Q235 mild steel in 1 M HCl environment. World News of Natural Sciences 15 (2017) 1-19
  • [35] H. Louis, J. Japari, A. Sadia, M. Philip, A. Bamanga, Photochemical screening and corrosion inhibition of Poupartia birrea back extracts as a potential green inhibitor for mild steel in 0.5 M H2SO4 medium. World News of Natural Sciences 10 (2017) 95-100
  • [36] M. E. Ikpi, F. E. Abeng, O. E. Obono, Adsorption and Thermodynamic Studies for Corrosion Inhibition of API 5L X-52 Steel in 2 M HCl Solution by Moxifloxacin. World News of Natural Sciences 9 (2017) 52-61
  • [37] T. O. Magu, V. M. Bassey, B. E. Nyong, O. E. Obono, N. A. Nzeata-Ibe, O. U. Akakuru, Inhibition studies of Spondias mombin L. in 0.1 HCl solution on mild steel and verification of a new temperature coefficient of inhibition efficiency equation for adsorption mechanism elucidation. World News of Natural Sciences 8 (2017) 15-26
  • [38] J. N. O. Ezeugo, O. D. Onukwuli, M. Omotioma, Optimization of corrosion inhibition of Picralima nitida leaves extract as green corrosion inhibitor for zinc in 1.0 M HCl. World News of Natural Sciences 15 (2017) 139-161
  • [39] Nkem B. Iroha, Abosede O. James, Adsorption behavior of pharmaceutically active dexketoprofen as sustainable corrosion Inhibitor for API X80 carbon steel in acidic medium. World News of Natural Sciences 27 (2019) 22-37
  • [40] M. E. Ikpi, F. E. Abeng, B. O. Okonkwo, Experimental and computational study of levofloxacin as corrosion inhibitor for carbon steel in acidic media. World News of Natural Sciences 9 (2017) 79-90
Document Type
article
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.psjd-3014c4b7-180e-4e33-aa5b-327764d5af62
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.