THE USE OF CHITIN AND CHITOSAN FOR THE REMOVAL OF REACTIVE BLACK 5 DYE

• Authors: Paula Szymczyk , Urszula Filipkowska , Tomasz Jóźwiak , Małgorzata Kuczajowska-Zadrożna
• Languages of publication: EN

Abstracts

EN

In this study, we investigated the effectiveness of Reactive Black 5 dye adsorption onto chitin and chitosan flakes. Adsorption capacity of chitin and chitosan, optimal pH of the adsorption process and reaction equilibrium time were determined. Results achieved were described with Freundlich, Langmuir and double Langmuir models. The pH value ensuring the highest dye adsorption effectiveness onto chitosan was pH 4. In turn, the highest dye adsorption effectiveness onto chitin was determined at pH 2, however considering that the pH value of industrial wastewater containing reactive dyes ranges from pH 3 to pH 4, further analyses with chitin were continued at pH 3. The time needed to reach the equilibrium concentration of dye was 360 min for chitin and 72 hours for chitosan. The study demonstrated that chitosan is the most effective sorbent of RB5. Its maximum adsorption capacity of the reactive dye accounted for 696.99 mg/g d.m., compared to 131.56 mg/g d.m. determined for chitin. Higher effectiveness of RB5 removal by chitosan is result of more number of amine groups in the chemical structure of this polymer, compared to chitin.

Keywords

EN

Reactive Black 5 (RB5); adsorption; chitin; chitosan

• Journal: Progress on Chemistry and Application of Chitin and its Derivatives
• Year: 2015
• Volume: 20
• Pages: 260-272

Contributors

author

Paula Szymczyk

• Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn ul Warszawska 117, 10 – 719 Olsztyn, Poland,

author

Urszula Filipkowska

• Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn ul Warszawska 117, 10 – 719 Olsztyn, Poland

author

Tomasz Jóźwiak

• Department of Environmental Engineering, University of Warmia and Mazury in Olsztyn ul Warszawska 117, 10 – 719 Olsztyn, Poland

author

Małgorzata Kuczajowska-Zadrożna

• Department of Biotechnology in Environmental Protection, University of Warmia and Mazury in Olsztyn ul. Słoneczna 45G,10–709Olsztyn, Poland

References

• 1. Altınışık A, Gür E, Seki Y; (2010) A natural sorbent,< i> Luffa cylindrica</i> for the removal of a model basic dye. J. Haz. Mat. 179(1), 658-664. DOI: 10.1016/j.jhazmat.2010.03.053
• 2. Papic S, Koprivanac N, Bozic AL, Metes A; (2004) Removal of some reactive dyes from synthetic wastewater by combined Al (III) coagulation/carbon adsorption process. Dyes and Pigments, 62, 291-298. DOI: 10.1016/S0143-7208(03)00148-7
• 3. Netpradita S, Thiravetyanb P, Towprayoona S, (2004) Evaluation of metal hydroxide sludge for reactive dye adsorption in a fixed-bed column system, Water Res. 38, 71-78. DOI: 10.1016/j.watres.2003.09.007
• 4. Burkinshaw SM, Kabambe O; (2011) Attempts to reduce water and chemical usage in the removal of bifunctional reactive dyes from cotton: Part 2 bis(vinyl sulfone), aminochlorotriazine/vinyl sulfone and bis(aminochlorotriazine/vinyl sulfone) dyes, Dyes and Pigments, 88, 220-229. DOI: 10.1016/j.dyepig.2010.07.001
• 5. Robinson T, McMullan G, Marchant R, Nigam P; (2001) Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative, Biores. Technol., 77, 247-255.
• 6. Carliell CM, Barclay SJ, Bucley CA; (1996) Treatment of exhausted reactive dyebath effluent using anaerobic digestion: Laboratory and full-scale trials, Water S.A, 22, 225-233.
• 7. Manu B, Chaudhari S; (2002) Anaerobic decolorisation of simulated textile wastewater containing azo dyes. Biores. Technol., 82, 225-231. DOI: 10.1016/S0960-8524(01)00190-0
• 8. Brookstein DS; (2009) Factors associated with textile pattern dermatitis caused by contact allergy to dyes, finishes, foams, and preservative, Dermatol. Clin., 27, 309–322. DOI: 10.1016/j.det.2009.05.001
• 9. Carneiro PA, Umbuzeiro GA, Oliveira DP, Zanoni MVB; (2010) Assessment of water contamination caused by a mutagenic textile effluent/dyehouse effluent bearing disperse dyes, J. Hazard. Mater., 174, 694–699.
• 10. Machad FM, Bergmann CP, Fernandes TH, Lima EC, Royer B, Calvete T, Fagan SB; (2011) Adsorption of Reactive Red M-2BE dye from water solutions by multi-walled carbon nanotubes and activated carbon, J. Hazard. Mater. 192(3), 1122-1131. DOI: 10.1016/j.jhazmat.2011.06.020
• 11. Ince NH, Stefan MI. Bolton JR; (1997) UV/H2O2 degradation and toxicity reduction of textile azo dyes: remazol Black-B, a case study, J. Adv. Oxid. Technol., 2, 442-448.
• 12. Ghoreishi SM, Haghighi R; (2003) Chemical catalytic reaction and biological oxidation for treatment of non-biodegradable textile effluent, Chem. Eng. J., 95(1), 163-169. DOI: 10.1016/S1385-8947(03)00100-1
• 13. Gómez V, Larrechi MS, Callao MP; (2007) Badania kinetyczne i adsorpcji barwnika usuwania kwasu z zastosowaniem węgla aktywnego, Chemosphere. 69 (7), 1151-1158. DOI: 10.1016/j.chemosphere.2007.03.076
• 14. Bailey SE, Olin TJ, Bricka RM, Adrian DD; (1999) A review of potentially low-cost sorbents for heavy metals, Water Res. 33 (11), 2469 – 2479.
• 15. Filipkowska U, Jóźwiak T, Rodziewicz J, Kuciejewska J; (2014) Zastosowanie kiszonki z kukurydzy Zea Mays L. do usuwania barwników z roztworów wodnych, Rocznik Ochrona Środowiska, Tom 15
• 16. Machida M, Kikuchi Y, Aikawa M, Tatsumoto H; (2004) Kinetics of adsorption and desorption of Pb(II) in aqueous solutions on activated carbon by two-site adsorption model, Colloid Surf. A: Physicochem. Eng. Aspects, 240, 179-186. DOI: 10.1016/j.colsurfa.2004.04.046
• 17. Wang S, Zhu ZH; (2005) Sonochemical treatment of fly ash for dye removal from wastewater, J Hazard Mater 126, 91-95. DOI: 10.1016/j.jhazmat.2005.06.009
• 18. Filipkowska U, Jóźwiak T; (2013) Application of chemically-cross-linked chitosan for the removal of Reactive Black 5 and Reactive Yellow 84 dyes from aqueous solutions, J. Polym. Eng. 33, 735-747. DOI: 10.1515/polyeng-2013-0166
• 19. Cheung WH, Szeto YS, McKay G; (2009) Enhancing the adsorption capacities of acid dyes by chitosan nano particles, Biores. Technol. 100(3), 1143-1148. DOI: 10.1016/j.biortech.2008.07.071
• 20. Crini G, Badot PM; (2008) Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature, Progress in Polym. Sci. 33(4), 399-447. DOI: 10.1016/j.progpolymsci.2007.11.001
• 21. Akkaya G, Uzun İ, Güzel F; (2007) Kinetics of the adsorption of reactive dyes by chitin, Dyes and Pigments, 73(2), 168-177. DOI: 10.1016/j.dyepig.2005.11.005
• 22. Gibbs G, Tobin JM, Guibal E; (2003) Sorption of Acid Green 25 on chitosan: influence of experimental parameters on uptake kinetics and sorption isotherms, J. Appl. Polym. Sci. 90(4), 1073-1080. DOI: 10.1002/app.12761
• 23. Azlan K, Wan Saime WN, Lai Ken L; (2009) Chitosan and chemically modified chitosan beads for acid dyes sorption, J. Environm. Sci. 21(3), 296-302. DOI: 10.1016/S1001-0742(08)62267-6
• 24. Gaffar MA, El-Rafie SM, El-Tahlawy KF; (2004) Preparation and utilization of ionic exchange resin via graft copolymerization of β-CD itaconate with chitosan, Carbohydr. Polym. 56(4), 387-396.
• 25. Štandeker S, Veronovski A, Novak Z, Knez Ž; (2011) Silica aerogels modified with mercapto functional groups used for Cu (II) and Hg (II) removal from aqueous solutions. Desalination, 269(1), 223-230.
• 26. Prado AG, Torres JD, Faria E A, Dias SC; (2004) Comparative adsorption studies of indigo carmine dye on chitin and chitosan, J. Colloid Interf. Sci. 277(1): 43-47. DOI: 10.1016/j.jcis.2004.04.056

• Document Type: article