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2017 | 13 | 113-121

Article title

Oxidation of Distyryl Ketone by Quinaldinium Chlorochromate – A Kinetic Study

Content

Title variants

Languages of publication

EN

Abstracts

EN
Oxidation of distyrylketone by quinaldinium chlorochromate [QnCC] in water and acetic acid medium has been studied under pseudo first order condition. The reaction shows unit order dependence each with respect to oxidant and hydrogen ion. The reaction with respect to substrate is found to be fractional order. The reaction rate decreases with increasing the concentration of Mn2+ ions. The reaction does not induce the polymerization of acrylonitrile. A possible mechanism has been proposed in the formation of cinnamic acid and Phenyl acetaldehyde.

Year

Volume

13

Pages

113-121

Physical description

Contributors

  • Department of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirappalli – 620 020, Tamil Nadu, India
  • Department of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirappalli – 620 020, Tamil Nadu, India

References

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  • [2] Sangita Sharma, Jayesh Ramani, Jasmin Bhalodia, Falguni Thakkar. Derchemica Sinica 2(4) (2011) 140-151.
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  • [5] Malani N., Pohani S., Baghmar M., Sharma P. K, Indian Journal of Chemistry, 47 (A), (2008) 1373-1376.
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  • [15] Wiberg, K. B., Oxidation in Organic Chemistry Part A, Academic Press New York . (1965)
  • [16] Littler, J. S., Waters, W. A., Oxidations of Organic compounds with quinquevalent Vanadium Part 1. General Survey and the Oxidation of Pinaco. J. Chem. Soc. 1299 (1959)
  • [17] Banfi, S., Cavazzini, M., Pozzi, G., Barkanova, S. V., Kaliya, O. L., J. Chem. Soc. Perkin Trans. 2 (2000) 879.
  • [18] Frost A. A., Pearson R. G., Kinetics and Mechanism. Wiley Eastern New Delhi, (1970)
  • [19] Peterson R. C., Markgraf J. H., Ross S. D., J. Am. Chem. Soc. 83 (1961) 3819-3823.

Document Type

article

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.psjd-07f5c3d1-5231-41f8-9dbd-91af072f0c03
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