Oxidation of Distyryl Ketone by Quinaldinium Chlorochromate – A Kinetic Study

• Authors: Seplappatty Kalimuthu Periyasamy , K. Saravanakumar
• Languages of publication: EN

Abstracts

EN

Oxidation of distyrylketone by quinaldinium chlorochromate [QnCC] in water and acetic acid medium has been studied under pseudo first order condition. The reaction shows unit order dependence each with respect to oxidant and hydrogen ion. The reaction with respect to substrate is found to be fractional order. The reaction rate decreases with increasing the concentration of Mn2+ ions. The reaction does not induce the polymerization of acrylonitrile. A possible mechanism has been proposed in the formation of cinnamic acid and Phenyl acetaldehyde.

Keywords

EN

Kinetics; Oxidation; Quinaldinium chlorochromate; distyrylketone

Discipline

• CHEMISTRY: CHEMISTRY

• Publisher: Scientific Publishing House „DARWIN”
• Journal: World News of Natural Sciences
• Year: 2017
• Volume: 13
• Pages: 113-121

Contributors

author

Seplappatty Kalimuthu Periyasamy

• Department of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirappalli – 620 020, Tamil Nadu, India

author

K. Saravanakumar

• Department of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirappalli – 620 020, Tamil Nadu, India

References

• [1] Sheila Srivastava, Parul Srivastava. Bull. Chem. Soc. Jpn. 57 (2010) 258-260.
• [2] Sangita Sharma, Jayesh Ramani, Jasmin Bhalodia, Falguni Thakkar. Derchemica Sinica 2(4) (2011) 140-151.
• [3] Chockalingam Karunakaran, Vaithiyalingam Chidambaranathan. Croatia Chemica Acta 74(1) (2001) 51-59.
• [4] Hauzachin Saunte, Girija S., Chaubey M. K., Mahanti. Croatia Chemica Acta, 83(3)(2010) 291-298.
• [5] Malani N., Pohani S., Baghmar M., Sharma P. K, Indian Journal of Chemistry, 47 (A), (2008) 1373-1376.
• [6] Sivamurugan V., Abraham Rajkumar, Banumathi Arabindoo, Murugesan, V., Indian. Journal of Chemistry 44(B) (2005) 144-147.
• [7] Sheik Mansoor, S., Syed Shafi, S. E. Journal of Chemistry, 6(S1) (2009) S522-S528.
• [8] Manikyamba, P., Aruna, K., Ultra sciences, 14 (3)(2002),483 -486.
• [9] Dae Dong Sung, Ananthakrishna Nadar P., Bull. Korean Chem. Soc. Vol. 20 (1999) No. 12 1487.
• [10] Sekar, K.G.,Periyasamy,S.K., Journal of Chemical and Pharmaceutical Research, 4(4) (2002) 2153-2161.
• [11] Nebahat Degirmenbasi, Beytiye Ozgun. Monatshefte furchemie. 135 (2004) 407.
• [12] Perrin, D. D., Armarego, W. L., Perin D. R., Purification of Organic Compounds. Pergamon Press Oxford, (1966).
• [13] Quinlan, J. E., Amis, E.S., J. Am. Chem. Soc. 77 (1955) 4187-4191.
• [14] Amis E. S., Solvent effects on reaction rates and mechanism, Academic Press, New York, 42, (1966)
• [15] Wiberg, K. B., Oxidation in Organic Chemistry Part A, Academic Press New York . (1965)
• [16] Littler, J. S., Waters, W. A., Oxidations of Organic compounds with quinquevalent Vanadium Part 1. General Survey and the Oxidation of Pinaco. J. Chem. Soc. 1299 (1959)
• [17] Banfi, S., Cavazzini, M., Pozzi, G., Barkanova, S. V., Kaliya, O. L., J. Chem. Soc. Perkin Trans. 2 (2000) 879.
• [18] Frost A. A., Pearson R. G., Kinetics and Mechanism. Wiley Eastern New Delhi, (1970)
• [19] Peterson R. C., Markgraf J. H., Ross S. D., J. Am. Chem. Soc. 83 (1961) 3819-3823.

• Document Type: article