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Article title

The Influence of Humidity and Soil Texture on the Degradation Process of Selected Herbicides Immobilized in Alginate Matrix in Soil under Laboratory Conditions

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The inflence of humidity and soil type on the degradation process of clomazone, metazachlor and pendimethalin immobilized in the alginate matrix were studied under laboratory condi tions, and herbicidal degradation parameters obtained for alginate systems and commercial formulations (Command 480 EC, Metazachlor 500 SC and Panida 330 SC) were compared. Two soils with different organic content were used in the experiment: loamy sand (S1) and sand (S2). The effect of soil humidity on the rate of herbicide degradation was assessed for soil S1 at 15% and 60% of maximum water holding capacity. Herbicides residues were analyzed using GC/MS method. The experimental data were fited to the mathematical model based on the fist-order reaction kinetics. There was no signifiant effect of soil type on the degradation rate of herbicides immobilized in the alginate matrix. For all alginate systems analyzed process was faster with an increased soil moisture. Formulation is a signifiant factor affecting the degradation process of herbicides in soil.
Physical description
17 - 11 - 2017
  • Arias-Estevez M., Lopez-Periago E., Martinez-Carballo E., Simal-Gandara J., Mejuto J. C., Garcia-Rio L., 2008. The mobility and degradation of pesticides in soils and the pollution of groundwater resources. Agric. Ecosyst. Environ., 123: 247-260.
  • Fernández-Pérez M., Garrido-Herrera F. J., González-Pradas E. 2011. Alginate and lignin-based formulations to control pesticides leaching in a calcareous soil. J. Hazard. Mater., 190: 794-801.
  • Flores-Céspedes F., Villafranca-Sánchez M., Pérez-Garcia S., Fernández-Pérez M., 2007. Modifying sorbents in controlled release formulations to prevent herbicides pollution. Chemosphere, 69: 785-794.
  • Foster D. K., Taylor W. A., Parsons R. G., 2006. Effects of adjuvants on the deposition, retention and efficacy of pesticides. Aspects Appl. Biol., 77, 1: 127-132.
  • Green J.M., Beestman G. B., 2007. Recently patented and commercialized formulation and adjuvant technology. Crop Prot., 26: 320-327.
  • Grygiel K., Sadowski J., Snopczyński T., Wysocki A., 2012. Herbicide residues in agricultural products and in the soil (in Polish). J. Eco. Health, 16, 40: 159-163.
  • (20.11.2016)
  • Kucharski M., Sadowski J., 2006. Influence of soil humidity on herbicide degradation - laboratory tests (in Polish). Prog. Plant Prot./Post. Ochr. Roślin. 46, 2: 750-753.
  • Kucharski M., Sadowski J., 2009. Influence of adjuvants on behavior of phenmedipham in plant and soil, Polish J. Agron. 1: 32-36.
  • Kucharski M., Sadowski J., Domaradzki K., 2012. Degradation rate of chloridazon in soil as influenced by adjuvants, J. Plant Prot. Res. 52, 1: 115-150.
  • Mervosh T. L., Sims G. K., Stoller E. W., 1995. Clomazone fate in soil as affected by microbal activity, temperature and soil moisture. J. Agric. Food Chem. 43: 537-543.
  • Method validation and quality control procedures for pesticide residues analysis in food and feed. 2011. Document No. SANCO/ 12495/2011. Supersedes Document No. SANCO/10684/2009. Implemented by 01.01.2012 (20.11.2016)
  • Mogul, M. G., Akin, H., Hasirci, N., Trantolo D. J., Gresser J. D., Wise D. L., 1996. Controlled release of biologically active agents for purposes of agricultural crop management. Resour. Conserv. Recy. 16: 289-320.
  • Pal R., Chakrabarti K., Chakraborty A., Chowdhury A., 2006. Degradation and effects of pesticides on soil microbiological parameters - review. Int. J. Agri. Res. 1, 3: 240-258.
  • Pernak J. Syguda A., Janiszewska D., Materna K., Praczyk T., 2011. Ionic liquids with herbicidal anions. Tetrahedron. 67: 4838-4844.
  • Pernak J., Niemczak M., Shamshina J. L., Gurau G., Głowacki G., Praczyk T., Marcinkowska K., Rogers R. D., 2015. Metsulfuron-methyl-based herbicidal ionic liquids. J. Agr. Food Chem. 13: 3357-3366.
  • Roy A., Singh S. K., Bajpai J. B., Bajpai A. K., 2014. Controlled pesticide release from biodegradable polymers. Cent. Eur. J. Chem. 12: 453-469.
  • Van der Werf H. M. G. 1996. Assessing the impact of pesticides on the environment. Agric. Ecosyst. Environ. 60: 81-96.
  • Włodarczyk M., Muszyńska A., Siwek H., Bartkowiak A. 2010. Optimization of production and characterization of hydrogel microcapsules with controlled release of selected herbicides (in Polish). Przem. Chem. 4, 581-586.
  • Włodarczyk M., Buchwał A., 2015. The behavior of metazachlor and clomazone immobilized in alginate matrix in water/ soil and water/bottom sediment systems (in Polish). Przem. Chem. 94, 6: 989-993.
  • Włodarczyk M., Siwek H. 2016. Influence of formulation on mobility of clomazone in soil. Bull. Environ. Contam. Toxicol. 97, 4: 582–587.
  • Włodarczyk M., 2016. Influence of the alginate matrix on the decay of the selected herbicides in the soil under field conditions (in Polish). Prog. Plant Prot./Post. Ochr. Roślin. 56, 3: 324-329.
  • Wrzosek, J., Gworek, B., Maciaszek D., 2009. Plant protection products and environmental protection (in Polish). Ochr. Śr. Zasobów Nat. 39: 75-88.
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