Asymmetric desymmetrization of organophosphorus compounds with organolithium-sparteine chiral bases

• Authors: Paweł Woźnicki
• Languages of publication: EN

Abstracts

EN

Chiral organophosphorus compounds are one of the main groups of ligands used in asymmetric homogenous catalysis. Ongoing progress in transition metal-catalyzed reactions requires that efficient methods for the synthesis of chiral phosphines and their derivatives are available. This review is focused on desymmetrization of heteroleptic tertiary phosphine derivatives via stereoselective lithiation using organolithium/sparteine complexes as chiral bases combined with oxidative homocoupling or trapping the P-chiral intermediates with electrophiles. The method has been used to obtain both known and new chiral ligands with application in stereoselective reactions catalyzed by transition metal complexes.

Keywords

EN

Organophosphorus compounds; Phosphines; Phosphine ligands; Deprotonation; Lithiation; Organolithium; Butyllithium; Sparteine

• Publisher: Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
• Journal: Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
• Year: 2019
• Volume: 74
• Issue: 1

Dates

published

2019

online

2020-06-17

Contributors

author

Paweł Woźnicki

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Identifiers

DOI

10.17951/aa.2019.74.1.65-92