Lignosulfonate as a byproduct of wood pulp production: A potential precursor for the preparation of functional hybrid materials

• Authors: Łukasz Klapiszewski , Tadeusz J. Szalaty , Tomasz Szatkowski , Teofil Jesionowski
• Languages of publication: EN

Abstracts

EN

Functional hybrid materials based on magnesium lignosulfonate and silica were obtained and characterized. Magnesium lignosulfonate is a common waste product of the wood pulp industry, while silica is a well-known inorganic material with exceptional physicochemical properties. In this study, silicas with a spherical particle shape were synthesized using a sol-gel method and alternatively in a nonpolar medium. Silica was found to improve the thermal and electrokinetic properties of the final products. The resulting lignosulfonate/silica hybrid materials were analyzed with the use of advanced techniques and measuring methods: scanning electron microscopy, a laser diffraction method enabling particle size measurements, Fourier transform infrared spectroscopy, elemental analysis, thermogravimetry, electrophoretic light scattering, zeta potential measurements, low-temperature nitrogen sorption, and colorimetric analysis. The results enabled the hybrid materials to be characterized from the point of view of potential applications in various branches of industry (for example as polymer fillers, electroactive blends and biosorbents). We additionally indicate new methods for the utilization of waste products, a category to which lignosulfonate certainly belongs.

Keywords

EN

lignosulfonate/silica hybrid materials, magnesium lignosulfonate, amorphous silica, development of natural products, physicochemical and structural properties.

• Publisher: Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
• Journal: Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
• Year: 2016
• Volume: 71
• Issue: 1

Dates

published

2016

online

24 - 05 - 2016

Contributors

author

Łukasz Klapiszewski

author

Tadeusz J. Szalaty

author

Tomasz Szatkowski

author

Teofil Jesionowski

References

• [1] K. Xie, Y. Yu and Y. Shi, Carbohydrate Polym., 78, 799, (2009).
• [2] S. Sequeira, D.V. Evtuguin and I. Portugal, Polym. Compos., 30, 1275, (2009).
• [3] W. Xiao, J. Xu, X. Liu, Q. Hu and J. Huang, J. Mater. Chem. B, 1, 3477, (2013).
• [4] G. Telysheva, T. Dizhbite, L. Jashina, A. Andersone, A. Volperts, J. Ponomarenko and N. Mironova-Ulmane, BioResources, 4, 1276, (2009).
• [5] Ł. Klapiszewski, M. Nowacka, G. Milczarek and T. Jesionowski, Carbohydrate Polym., 94, 345, (2013).
• [6] T. Jesionowski, Ł. Klapiszewski and G. Milczarek, J. Mater. Sci., 49, 1376, (2014).
• [7] R. Núñez-Flores, B. Giménez, F. Fernández-Martín, M.E. López-Caballero, M.P. Montero and M.C. Gómez-Guillén, Food Hydrocolloids, 27, 60, (2011).
• [8] H. Luo, Q. Shen, F. Ye, Y.F. Cheng, M. Mezgebe and R.J. Qin, Mater. Sci. Eng. C, 32, 2001, (2012).
• [9] W. Stöber, A. Fink and E. Bohn, J. Colloid Interface Sci., 26, 62, (1968).
• [10] I.A.M. Ibrahim, A.A.F. Zikry and M.A. Sharaf, J. Am. Sci., 6, 985, (2010).
• [11] Ł. Klapiszewski, M. Królak and T. Jesionowski, Cent. Eur. Journal of Chemistry, 12, 173, (2014).
• [12] J. Żurawska, A. Krysztafkiewicz and T. Jesionowski, Surf. Interface Anal., 35, 914, (2003).
• [13] T. Jesionowski, J. Żurawska, A. Krysztafkiewicz, M. Pokora, D. Waszak and W. Tylus, Appl. Surf. Sci., 205, 212, (2002).
• [14] T. Jesionowski, Powder Technol., 127, 56, (2002).
• [15] T. Jesionowski, J. Mater. Sci., 37, 5275, (2002).
• [16] G. Wypych, Handbook of Fillers, Chemical Technology Publishing, 2010.
• [17] M. Fišerová, E. Opálená and M. Maholányiová, Cellulose Chem. Technol., 47, 583, (2013).
• [18] M.J. Feria, J.C. Garcia, M.A.M. Zamudio, J.L. Gomide, J.L. Colodette and F. López, Cellulose Chem. Technol., 47, 595, (2013).
• [19] K. Chakrabarty, K.V. Krishna, P. Saha and A.K. Ghoshal, J. Membrane Sci., 330, 135, (2009).
• [20] W.O.S. Doherty, P. Mousavioun and C.M. Fellows, Ind. Crop. Prod., 33, 259, (2011).
• [21] G. Lota and G. Milczarek, Electrochem. Commun., 13, 470, (2011).
• [22] N.E.El Mansouri and J. Salvad´o, Ind. Crop. Prod., 24, 8, (2006).
• [23] M.Y.A. Mollah, P. Palta, T.R. Hess, R.K. Vempati and D.L. Cocke, Cement Concrete Res., 25, 671, (1995).
• [24] S.A. Gundersen, Ø. Sæther and J. Sjoblom, Colloid Surface A, 186, 141, (2001).
• [25] E.A. Borges da Silva, M. Zabkova, J.D. Araújo, C.A. Cateto, M.F. Barreiro, M.N. Belgacem, and A.E. Rodrigues, Chem. Eng. Res. Des., 87, 1276, (2009).
• [26] J. Roszyk, O. Nowosielski and W. Breś, Acta Agrophys., 7, 991, (2006).
• [27] Ł. Klapiszewski, M. Mądrawska and T. Jesionowski, Physicochem. Probl. Miner. Process., 48, 463, (2012).
• [28] D. Yea, M. Zhanga, L. Gana, Q. Lia and X. Zhanga, Int. J. Biol. Macromol., 60, 77, (2013).
• [29] D. Yea, X. Jianga, C. Xiaa, L. Liua and X. Zhanga, Carbohydrate Polym., 89, 876, (2012).
• [30] D. Wanga, Y. Linc and W. Dua, Int. Biodeter. Biodegr., 85, 365, (2013).
• [31] K. Szwarc-Rzepka, B. Marciniec and T. Jesionowski, Adsorption, 19, 483, (2013).
• [32] H. Liu, S. Fu, H. Li and H. Zhan, Ind. Crop. Prod., 30, 287, (2009).
• [33] D. Yang, X. Qiu, Y. Pang and M. Zhou, J. Dispersion Sci. Technol., 29, 1296, (2008).
• [34] X. Ouyang, L. Ke, X. Qiu, Y. Gu and Y. Pang, J. Dispersion Sci. Technol., 30, 1, (2009).
• [35] Y. Ge, Z. Li, Y. Pang and X. Qiu, Int. J. Biol. Macromol., 52, 300, (2013).
• [36] D. Yang, X. Qiu, M. Zhou and H. Lou, Energy Convers. Manage., 48, 2433, (2007).
• [37] Ł. Klapiszewski, M. Nowacka, K. Szwarc-Rzepka and T. Jesionowski, Physicochem. Probl. Miner. Process., 49, 497, (2013).
• [38] M. Nowacka, Ł. Klapiszewski, M. Norman and T. Jesionowski, Cent. Eur. J. Chem., 11, 1860, (2013).

Identifiers

DOI

10.17951/aa.2016.71.1.47