Mesoporous silica functionalized with phenylamino and gluconamide groups: synthesis, characterization and use for sorption of diclofenac

• Authors: Mariusz Barczak
• Languages of publication: EN

Abstracts

EN

Synthesis of SBA-15 mesoporous organosilicas functionalized by phenylamino and gluconamide groups is reported. The organosilicas have been synthesized by co-condensation of proper monomers in the presence of Pluronic P123, and characterized by nitrogen sorption, X-ray diffractometry, elemental analysis, and FTIR spectroscopy to get detailed information about their porous structure, ordering and presence of introduced functional groups. The obtained materials were tested as sorbents of model pharmaceutical (diclofenac) to verify a potential application for removal of pharmaceutical: the observed static sorption capacities were ~50mg/g and ~130mg/g, for phenylamino- and gluconamidefunctionalized samples, respectively, while for pristine sample no adsorption was observed.

Keywords

EN

• Publisher: Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
• Journal: Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
• Year: 2015
• Volume: 70
• Issue: 2

Dates

published

2015

online

2016-02-15

Contributors

author

Mariusz Barczak

References

• J. Zhao, F. Gao, Y. Fu, W. Jin, P. Wang, D.D. Zhao, Chemical Communications, 7, 752-753, (2002).
• J.F. Diaz, K.J. Balkus, Journal of Molecular Catalysis B - Enzymatic, 2-3, 115-126, (1996).
• S. Ernst, M. Hartmann, S. Munsch, Studies in Surface Science and Catalysis, 135, 4566-4573, (1996).
• J. Deere, E. Magner, J.G. Wall, B.K. Hodnett, Chemical Communications, 465-465, (2001).
• A. Vinu, V. Murugesan, O. Tangerman, M. Hartmann, Chemistry of Materials, 16, 3056-3065, (2004).
• A. Vinu, C. Streb, V. Murugesan, M. Hartmann, The Journal of Physical Chemistry B, 107, 8297-8299, (2003).
• M. Hartmann, Chemistry of Materials, 17, 4577, (2005).
• A. Popat, S.B. Hartono, F. Stahr, J. Liu, S.Z. Qiao, G. Qing Max Lu, Nanoscale, 3, 2801-2818, (2011).
• C.-H. Lee, T.-S. Lin, C.-Y. Mou, Nano Today 4, 165-179, (2009).
• D. Knopp, D. Tang, R. Niessner, Analitica Chimica Acta 647, 14-30, (2009).
• D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Science, 279, 548-552, (1998).
• D. Zhao, Q. Huo, J. Feng, B.F. Chmelka, G.D. Stucky, Journal of the American Chemical Society, 120, 6024-6036, (1998).
• C.G. Goltner, S. Henke, M.C. Weissenberger, M. Antonietti, Angewandte Chemie International Edition, 37, 613-616, (1998).
• F. Zhang, Y. Yan, H. Yang, Y. Meng, C. Yu, B. Tu, D. Zhao, The Journal of Physical Chemistry B, 109, 8723-8732, (2005).
• V. Antochshuk, O. Olkhovyk, M. Jaroniec, I.S. Park, R. Ryoo, Langmuir, 19, 3031-3034, (2003).
• J. Andersson, J. Rosenholm, S. Areva, M. Linden, Chemistry of Materials, 16, 4160-4167, (2004).
• O. Olkhovyk, V. Antochshuk, M. Jaroniec, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 236, 69-72, (2004).
• G.Q. Lu, X.S. Zhao, Nanoporous materials – an overview, [in:] G.Q. Lu, X.S. Zhao ed., Nanoporous Materials: Science and Engineering, Imperial College Press, London 2004.
• M. Vallet-Regí, F. Balas, D. Acros, Angewandte Chemie International Edition, 46, 7548-7558, (2007).
• M. Kruk, M. Jaroniec, C.H. Ko, R. Ryoo, Chemistry of Materials, 12, 1961-1968, (2000).
• D. Zhao, J. Sun, Q. Li, G.D. Stucky, Chemistry of Materials, 12, 275-279, (2000).
• M. Barczak, E. Skwarek, W. Janusz, A. Dąbrowski, S. Pikus, Applied, Surface Science 256, 5370-5375, (2010).
• M. Barczak, A. Dąbrowski, S. Pikus, J. Ryczkowski, P. Borowski, M. Kozak, Adsorption 16, 457-463, (2010).
• M. Barczak, S. Pikus, B. Skrzydło-Radomańska, A. Dąbrowski, Adsorption 15, 278-286, (2009).
• M. Barczak, P. Borowski, A. Dąbrowski, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 347, 114-120, (2009).

Identifiers

DOI

10.17951/aa.2015.70.2.145