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Title variants
Utlenianie (E)-2,5-dimetylo-3-heksenu tlenem singletowym
Languages of publication
Abstracts
A solution of (E)-2,5-dimethyl-3-hexene (͟1) in dichloromethane
containing tetraphenylporphine as a photosensitizer was illuminated,
under an oxygen atmosphere, with a sodium lamp, and
3-hydroperoxy-2,5-dimethyl-4-hexene (͟2) was obtained. It
partially rearranged in CDCl₃, to give a mixture of hydroperoxide
(͟2) and (E)-2-hydroperoxy-2,5-dimethyl-3-hexene (͟3),
in the ratio 2 : 3.
containing tetraphenylporphine as a photosensitizer was illuminated,
under an oxygen atmosphere, with a sodium lamp, and
3-hydroperoxy-2,5-dimethyl-4-hexene (͟2) was obtained. It
partially rearranged in CDCl₃, to give a mixture of hydroperoxide
(͟2) and (E)-2-hydroperoxy-2,5-dimethyl-3-hexene (͟3),
in the ratio 2 : 3.
W wyniku fotochemicznie inicjowanego procesu utleniania (E)-
-2 , 5-dimetylo-3-heksenu otrzymano 3-hydroperoksy-2,5-dimetylo-4-
-heksen. Na podstawie badań ¹H-NMR stwierdzono, że ten nowo otrzymany
wodoronadtlenek ulega częściowemu samorzutnemu przegrupowaniu
w CDCl₃ do (E)-2-hydroperoksy-2, 5-dimetylo-3-heksenu.
-2 , 5-dimetylo-3-heksenu otrzymano 3-hydroperoksy-2,5-dimetylo-4-
-heksen. Na podstawie badań ¹H-NMR stwierdzono, że ten nowo otrzymany
wodoronadtlenek ulega częściowemu samorzutnemu przegrupowaniu
w CDCl₃ do (E)-2-hydroperoksy-2, 5-dimetylo-3-heksenu.
Keywords
Publisher
Year
Volume
Physical description
Dates
published
1993
Contributors
author
References
Document Type
Publication order reference
Identifiers
URI
http://hdl.handle.net/11089/15297
YADDA identifier
bwmeta1.element.hdl_11089_15297
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