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2001 | 99 | 6 | 665-672

Article title

Diffusion of Potassium on the W(112) Plane Preadsorbed by Ni Atoms: Field Emission Current Fluctuations - Autocorrelation Study

Content

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Languages of publication

EN

Abstracts

EN
Diffusion of potassium adsorbate on the W(112) plane with preadsorbed nickel was investigated by means of the autocorrelation function of field emission current fluctuations. A comparison of the experimental autocorrelation function with that of a theoretical calculation by Gesley and Swanson gives the surface diffusion coefficient of potassium. From its temperature dependence the diffusion activation energy at several Ni pre-coverages for a constant potassium coverage (Θ_K=0.4) is derived. The dependence of the activation energy for potassium surface diffusion on the nickel coverage - first reduction and then an increase with increasing Ni coverage - is observed. This is in agreement with the results obtained from the spectral analysis of the field emission current fluctuations of the same system. The decrease is understood to be a result of the smoothing effect caused by Ni atoms on the W(112) plane.

Keywords

Contributors

author
  • Institute of Experimental Physics, University of Wrocław, Pl. Maxa Borna 9, 50-204 Wrocław, Poland
  • Institute of Experimental Physics, University of Wrocław, Pl. Maxa Borna 9, 50-204 Wrocław, Poland
author
  • Fakultät für Physik und Geowissenschaften, Universität Leipzig, Linnéstr. 5, 7010 Leipzig, Germany

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.bwnjournal-article-appv99n604kz
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