Experimental and Theoretical Spectroscopic Studies on Selected Igepals

• Authors: G. Pasterna , T. Kupka , R. Wrzalik , K. Pasterny , J.S. Blicharski
• Languages of publication: EN

Abstracts

EN

Several nonionic igepals characterized by the formula (C_{m}H_{2m+1})-C_{6}H_{4} (OCH_{2}CH_{2})_{n}OH were investigated by high resolution NMR and IR spectroscopy. Gauge invariant atomic orbital density functional theory NMR calculations on model molecules in the gas phase additionally supported the assignment of experimental carbon signals. Different orientations of individual sub-units of an aliphatic chain relative to external magnetic field and trans-gauche transitions were assumed to explain complex patterns of carbon spectra in the aliphatic region of igepals with linear alkyl chain.

Keywords

EN

33.20.Ea; 32.30.Dx; 31.15.Ar

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2000
• Volume: 98
• Issue: 5
• Pages: 651-654

Dates

published

2000-11

Contributors

author

G. Pasterna

• Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland

author

T. Kupka

• Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland

author

R. Wrzalik

• Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland

author

K. Pasterny

• Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland

author

J.S. Blicharski

• Institute of Physics, Jagiellonian University, Reymonta 4, 30-086 Kraków, Poland