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2000 | 98 | 4 | 363-371
Article title

Vibrational Corrections to Transition Properties

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Languages of publication
EN
Abstracts
EN
The vibrational contributions to second-order transition properties are considered in the framework of the Born-Oppenheimer approximation. It is shown that the usual formula for vibrational second-order transition matrix elements is incomplete and needs to be supplemented by a term of purely vibrational origin. This pure vibrational contribution is calculated for vibrational transition polarizabilities in LiH and BeF and found to be quite significant. Its inclusion in theoretically calculated data for the Raman intensities appears to be necessary.
Keywords
EN
Publisher

Year
Volume
98
Issue
4
Pages
363-371
Physical description
Dates
published
2000-10
received
2000-08-17
Contributors
author
  • Institute of Chemistry, Silesian University, Szkolna 9, 40-006 Katowice, Poland
author
  • Department of Quantum Chemistry, Institute of Chemistry Nicolaus Copernicus University, Gagarina 7, 87-100 Toruń, Poland
References
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv98z405kz
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