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1997 | 92 | 3 | 507-516
Article title

Nuclear Quadrupole Coupling Tensor of Ch_{2}Cl_{2}: Comparison of Quadrupolar and Structural Angles in Methylene Halides

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EN
Abstracts
EN
Nuclear quadrupole hyperfine structure in 2_{1,2} ← 3_{0,3} and 1_{1,1} ← 2_{0,2} rotational transitions of CH_{2}^{35}Cl_{2} at 9.2 and 15.9 GHz, respectively, was measured with a newly constructed pulsed supersonic beam, cavity Fourier transform microwave spectrometer. All components of nuclear quadrupole splitting tensors of the chlorine nuclei in inertial and in principal quadrupole axes were determined. It is shown that in methylene halide molecules nuclear quadrupole information leads to a value for ∠(XCX) which is systematically larger than ∠(XCX) defined by the positions of the nuclei. Some novel features of the spectrometer are also described.
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EN
Publisher

Year
Volume
92
Issue
3
Pages
507-516
Physical description
Dates
published
1997-09
received
1997-04-29
Contributors
author
  • Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warszawa, Poland
  • Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warszawa, Poland
  • Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warszawa, Poland
References
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Publication order reference
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YADDA identifier
bwmeta1.element.bwnjournal-article-appv92z304kz
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