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Abstracts
New mixed-valent copper chalcogenides BaCuS_{3-x} and K_{3}Cu_{8}X_{6} with X=Se or Te and KCu_{3}Se_{2}, with chemical patterns corresponding to the recently investigated K_{3}Cu_{8}S_{6} and KCu_{3}S_{2}, were synthesized. For these new samples the results of resistivity and magnetic susceptibility measurements are presented. For BaCuS_{3-x}, K_{3}Cu_{8}Se_{6} and KCu_{3}Se_{2} the metal-insulator transition is observed with the low temperature phase being metallic, which is untypical, whereas K_{3}Cu_{8}Te_{6} is a metal in the investigated temperature range. The temperature dependence of magnetic susceptibility of the studied samples testifies to their diamagnetic or weakly paramagnetic behaviour.
Journal
Year
Volume
Issue
Pages
405-408
Physical description
Dates
published
1997-02
Contributors
author
- Institute of Physics, A. Mickiewicz University, Umultowska 85, 61-614 Poznań, Poland
author
- Institute of Physics, A. Mickiewicz University, Umultowska 85, 61-614 Poznań, Poland
author
- Department of Physics, Kharkov State University, Kharkov, Ukraine
author
- Institute of Physics, Silesian University, Uniwersytecka 4, 40-007 Katowice, Poland
author
- Institute of Physics, A. Mickiewicz University, Umultowska 85, 61-614 Poznań, Poland
References
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Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv91z238kz