Influence of N_{3}^{-} Ions on Chemiluminescence of the Eu(II)/Eu(III)-H_{2}O_{2} System

• Authors: M. Elbanowski , K. Staninski , M. Kaczmarek , S. Lis
• Languages of publication: EN

Abstracts

EN

The basic system of chemiluminescence investigations of relevant biological and inorganic compounds consists of Eu(II)/Eu(III) - H_{2}O_{2}. In these studies the increase in Eu(III) ion emission intensity usually results from an effective complexation reaction. In the present study, the N_{3}¯ ions are used as a ligand. The increase in the chemiluminescence intensity of the Eu(III) ion, the pH influence (in the range of 4.5-7.5) on the chemiluminescence intensity of the Eu(III) ion, as well as the quenching of the ^{5}D_{0} excited state of the Eu(III) ion are observed due to N_{3}¯ complexation. Taking into account the well-known Fenton system [Fe(II)/Fe(III) - H_{2}O_{2}], containing additionally the N_{3}¯, Eu(III) or Sm(III) ions, we found that the Eu(III) or Sm(III) ions were excited as a result of energy transfer process. A mechanism of the studied reactions is proposed.

Keywords

EN

78.60.Ps; 78.55.-m

Discipline

• 78.55.-m: Photoluminescence, properties and materials(for time resolved luminescence, see 78.47.jd)
• 78.60.Ps: Chemiluminescence(see also 42.55.Ks Chemical lasers)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 1996
• Volume: 90
• Issue: 1
• Pages: 101-108

Dates

published

1996-07

Contributors

author

M. Elbanowski

• Department of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

author

K. Staninski

• Department of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

author

M. Kaczmarek

• Department of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

author

S. Lis

• Department of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

Identifiers

DOI

10.12693/APhysPolA.90.101