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1996 | 89 | 4 | 547-554
Article title

Molecular Correlations in Liquid mono- and Dlichloroalkanes

Content
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Languages of publication
EN
Abstracts
EN
This paper reports results of the X-ray diffraction structural studies of a series of liquid monochloroalkanes (chlorohexane, chlorooctane, chlorodecane, chlorododecane) and dichloroalkanes (1, 6-dichlorohexane, 1, 8-dichlorooctane, 1, 10-dichlorodecane, 1, 12-dichlorododecane) performed at 20 and 40°C. From the X-ray diffraction patterns, obtained using Mo K_{α} radiation of the wavelength λ = 0.7107 Å, the mean angular distributions of intensities were determined. Then, the functions of radial distributions of electron density were numerically found using Fourier analysis. The mean structural parameters of the studied liquids (the inter- and intramolecular distances, the radii of coordination spheres, the coordination numbers) and the local arrangement of their molecules were established. The intermolecular arrangements in the studied liquid mono- and dichloroalkanes were found to be similar. Correlations were found between certain physical and chemical properties of the studied compounds and the spatial arrangement of their molecules.
Keywords
EN
Publisher

Year
Volume
89
Issue
4
Pages
547-554
Physical description
Dates
published
1996-04
received
1995-07-27
(unknown)
1995-12-05
Contributors
author
  • Non-Crystalline Materials Division, Institute of Physics, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań 2, Poland
author
  • Non-Crystalline Materials Division, Institute of Physics, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań 2, Poland
References
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv89z409kz
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