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The interfaces between nonmagnetic CdTe quantum wells and semimagnetic barriers of Cd_{1-x}Mn_{x}Te were investigated for several well widths by low temperature photoluminescence and photoluminescence excitation spectroscopy. Specially designed Cd_{1-x}Mn_{x}Te/CdTe/Cd_{1-y}Mg_{y}Te structures enable us to distinguish the quality of the semimagnetic normal and inverted interfaces. The normal interface shows to have a better structural quality than the inverted interface.