EN
High quality epitaxial layers of GaAs, InP, AlAs, InGaAs, InGaP, InGaAlP have been grown by low-pressure metalorganic chemical vapor deposition using TMIn, TMGa, TMAl and the less hazardous group V precursors, ΤΒA, TBP. Excellent morphology was obtained for GaAs and InP in the temperature ranges of 570-650°C and 520-650°C, respectively. The V/III ratio as low as 1.5 was used to grow epilayers of InP. The 77 K mobility of InGaAs lattice matched to InP (grown with ΤΒA) was 72360 cm^{2}/(V s) for n = 1.5 × 10^{15}/cm^{-3} and a thickness of 2 μm. Comparable photoluminescence parameters of InGaP between layers grown with TBP and PH_{3} were achieved, but for InGaAlP (TBP) photoluminescence intensity was significantly lower than for InGaAlP (PH_{3}). The promising results allow one to apply of ΤΒA and TBP for developing of device structures.