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1995 | 88 | 3 | 435-444
Article title

Franck-Condon Effects in Resonance Raman Spectra of TCNQ^{-} and C_{10}H^{+8} Radicals. A Search for Dushinsky Rotation of Totally Symmetric Modes

Content
Title variants
Languages of publication
EN
Abstracts
EN
The resonance Raman spectra of tetracyanoquinodimethane anion (TCNQ^{-}) and naphthalene cation (C_{10}H^{+8}) are analyzed in terms of theoretical model based on the Franck-Condon effects. The model includes also the effect of rotation of totally symmetric normal coordinates upon electronic excitation to the resonant state (Dushinsky effects). It is shown that such a simple model accounts correctly for the available resonance Raman spectra for TCNQ^{-} and C_{10}H^{+8} radicals. The possible model refinements such as vibronic coupling effects are also briefly discussed.
Keywords
EN
Year
Volume
88
Issue
3
Pages
435-444
Physical description
Dates
published
1995-09
received
1995-03-22
(unknown)
1995-05-18
References
Document Type
Publication order reference
YADDA identifier
bwmeta1.element.bwnjournal-article-appv88z302kz
Identifiers
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