Journal
Article title
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Abstracts
The hyperpolarizabilities of several pseudoazulenes are evaluated using a semiempirical quantum chemistry package MOPAC-93 and compared with hyperpolarizabilities of simple molecules like chloroform, benzene, naphthalene and azulene. The third-order hyperpolarizability γ is measured for a derivative of 1,2-5,6 dibenzoxalene using a femtosecond Z-scan method at 800 nm. The resulting hyperpolarizability of 1.7×10-34 esu corroborates the theoretical prediction that pseudoazulene structures behave similar to other aromatic molecules provided the experiments are carried out in a non-resonant regime.
Journal
Year
Volume
Issue
Pages
411-416
Physical description
Dates
published
1995-08
received
1995-04-05
Contributors
author
- Laser Physics Centre, Research School of Physical Sciences and Engineering, Australian National University, Canberra, ACT 0200, Australia
author
- Laser Physics Centre, Research School of Physical Sciences and Engineering, Australian National University, Canberra, ACT 0200, Australia
author
- Laser Physics Centre, Research School of Physical Sciences and Engineering, Australian National University, Canberra, ACT 0200, Australia
author
- Laser Physics Centre, Research School of Physical Sciences and Engineering, Australian National University, Canberra, ACT 0200, Australia
author
- Institute of Physical and Theoretical Chemistry, Technical University of Wrocław, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
References
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv88z217kz