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1995 | 88 | 2 | 349-357
Article title

Structure and Spectroscopic Behaviour of Adduct of 2,6-dichloro-4-nitrophenol with 2,4,6-trimethylpyridine

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EN
Abstracts
EN
2,4,6-trimethylpyridinium 2,6-dichloro-4-nitrophenolate crystallizes in monoclinic system, space group Ρ2_{1}/c, a = 7.534(2), b = 26.673(5), c = 8.452(2) Å, β = 116.16(3)°, Z = 4. The planar molecules are arranged in the lattice as antiparallel oriented pairs with the symmetry centre. The O^{-}···Η-Ν^{+} hydrogen bonds are relatively long, 2.686(4) Å. The C-O bond length, 1.250(4) A, indicates an extended charge separation. The IR and UV-VIS spectra in KBr pellets confirm the ion pairs to be present in the solid state.
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Year
Volume
88
Issue
2
Pages
349-357
Physical description
Dates
published
1995-08
received
1995-04-07
Contributors
author
  • Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland
  • Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland
author
  • Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland
References
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Publication order reference
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YADDA identifier
bwmeta1.element.bwnjournal-article-appv88z210kz
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