^{13}C High Resolution NMR Study of Methyl-Diethyl Sulfonium TCNQ 1:2 Complex

• Authors: L. Firlej , J. Pęcherz , P. Bernier
• Languages of publication: EN

Abstracts

EN

Solid state high resolution ^{13}C NMR studies of a 1 : 2 charge transfer complex of TCNQ with diethyl-methyl sulfonium S + Et_{2}Me(TCNQ)_{2} are presented. The metallic shifts of TCNQ resonances are interpreted as due to the Pauli paramagnetism of conducting electrons and quantitatively con­nected with inhomogeneous spin density distribution over (TCNQ2)¯ dimer. A singularity of NMR parameters at T = 330 K is observed and described as a structural phase transition occurring in the S + Et_{2}Me cation sublattice.

Keywords

EN

76.60.-k; 76.30.-v

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 1995
• Volume: 87
• Issue: 4-5
• Pages: 829-834

Dates

published

1995-04

Contributors

author

L. Firlej

• Groupe de Dynamique des Phases Condensées, Université Montpellier II, URA 233 34095 Montpellier, France

author

J. Pęcherz

• Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, Poland

author

P. Bernier

• Groupe de Dynamique des Phases Condensées, Université Montpellier II, URA 233 34095 Montpellier, France