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1995 | 87 | 4-5 | 829-834
Article title

^{13}C High Resolution NMR Study of Methyl-Diethyl Sulfonium TCNQ 1:2 Complex

Content
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Languages of publication
EN
Abstracts
EN
Solid state high resolution ^{13}C NMR studies of a 1 : 2 charge transfer complex of TCNQ with diethyl-methyl sulfonium S + Et_{2}Me(TCNQ)_{2} are presented. The metallic shifts of TCNQ resonances are interpreted as due to the Pauli paramagnetism of conducting electrons and quantitatively con­nected with inhomogeneous spin density distribution over (TCNQ2)¯ dimer. A singularity of NMR parameters at T = 330 K is observed and described as a structural phase transition occurring in the S + Et_{2}Me cation sublattice.
Keywords
EN
Publisher

Year
Volume
87
Issue
4-5
Pages
829-834
Physical description
Dates
published
1995-04
Contributors
author
  • Groupe de Dynamique des Phases Condensées, Université Montpellier II, URA 233 34095 Montpellier, France
author
  • Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, Poland
author
  • Groupe de Dynamique des Phases Condensées, Université Montpellier II, URA 233 34095 Montpellier, France
References
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv87z422kz
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