Electronic Correlations and Electron-Molecular Vibration Coupling in Pentamerized Charge Transfer Crystals

• Authors: V. Yartsev , C. Garrigou-Lagrange
• Languages of publication: EN

Abstracts

EN

A cluster approach is used for a theoretical description of the optical properties of pentamerized low-dimensional molecular crystals. Electronic correlations are taken into account explicitly in the Hubbard model for 1, 2, 3, 4 and 5 electrons in a linear pentamer, as well as coupling of electrons to the totally symmetric intramolecular vibrations. Calculated absorbance is compared to the measured one in pentamerized salt of TCNQ and TTF molecules.

Keywords

EN

71.45.Gm; 78.30.Jw

Discipline

• 78.30.Jw: Organic compounds, polymers
• 71.45.Gm: Exchange, correlation, dielectric and magnetic response functions, plasmons

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 1995
• Volume: 87
• Issue: 4-5
• Pages: 819-822

Dates

published

1995-04

Contributors

author

V. Yartsev

• Centro de Física, IVIC, Apartado 21827, Caracas 1020-A, Venezuela
• Centre de Recherche Paul Pascal, CNRS, 33600 Pessac, France

author

C. Garrigou-Lagrange

• Centre de Recherche Paul Pascal, CNRS, 33600 Pessac, France

Identifiers

DOI

10.12693/APhysPolA.87.819