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Abstracts
We analyze the effect of on-site and on-bond electron-phonon (e-ph) coupling in different classes of quasi one-dimensional (1D) solids in terms of a single model. The model was originally developed to account for e-ph coupling in charge transfer crystals and to interpret their vibrational spectra. The same model is extended to conjugated polymers, showing that important information about the electronic structure can be obtained through a careful analysis of vibrational data. Evidence of e-ph coupling in the spectra of halogen-bridged transition-metal complexes is also presented. The unified model thus applies to different classes of 1D systems and yields transferable e-ph coupling constants.
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Journal
Year
Volume
Issue
Pages
735-742
Physical description
Dates
published
1995-04
Contributors
author
- Dip. Chim. Gen. Inorg. Anal. e Chim. Fisica, Parma University, Parma, Italy
author
- Dip. Chim. Gen. Inorg. Anal. e Chim. Fisica, Parma University, Parma, Italy
author
- Department of Chemistry, Princeton University, Princeton, NJ, USA
References
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Publication order reference
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YADDA identifier
bwmeta1.element.bwnjournal-article-appv87z405kz