Journal
Article title
Authors
Title variants
Languages of publication
Abstracts
Nonlinear optical dichroism technique is shown to be an useful tool for the 1D conjugated polymer chain orientation study. When done as a function of rotation angle it gives the order parameters. These parameters can be also obtained by coupling this technique with linear dichroism method. The technique is illustrated by third harmonic generation on epitaxied polydiacetylene thin films either on single-crystalline or on preoriented ultrathin films by rubbing. Whereas an almost perfect orientation is obtained in the case of epitaxy of p-DCH, poly [1,6-bis(N-carbazolyl)-2,4-hexadiyne], on KAP, potassium acid phthalate, single crystal, this is smaller for epitaxy on preoriented substrate. The results are correlated with thin film texture measurements with X-rays. A good overall agreement is seen except that X-ray data show better order than nonlinear optical dichroism. A possible origin of this difference is shortly discussed.
Discipline
- 78.20.-e: Optical properties of bulk materials and thin films(for optical properties related to materials treatment, see 81.40.Tv; for optical materials, see 42.70-a; for optical properties of superconductors, see 74.25.Gz; for optical properties of rocks and minerals, see 91.60.Mk; for optical properties of specific thin films, see 78.66.-w)
- 42.65.-k: Nonlinear optics
Journal
Year
Volume
Issue
Pages
713-722
Physical description
Dates
published
1995-04
Contributors
author
- Commissariat à l'Energie Atomique, Direction des Technologies Avancées LETI, DEIN/SPE/GCO, CE Saclay, 91191 Gif Sur Yvette Cedex, France
author
- Commissariat à l'Energie Atomique, Direction des Technologies Avancées LETI, DEIN/SPE/GCO, CE Saclay, 91191 Gif Sur Yvette Cedex, France
author
- Instutit de Physique et de Science des Materiaux, 23, rue du Loess, 67037 Strasbourg, France
author
- Department of Mining and Electrical Engineering, Mc Gill University, 3450 University Street, Montréal PQ, Canada H3A 2A7
References
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv87z403kz