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X-ray bremsstrahlung isochromat of amorphous SiO_{2} deposited on Si crystal was measured in an energy range up to 250 eV above the threshold. Extended X-ray bremsstrahlung isochromat he structure (EXBIFS) was observed up to 150 eV for SiO_{2} studied. The Fourier transform of EXBIFS showed two peaks originated from first and second neighbors around silicon and oxygen ions. Model calculations of EXBIFS of amorphous SiO_{2} were performed in terms of single scattering of spherical waves and compared with experimental results.