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1994 | 85 | 5 | 805-812
Article title

Core Polarization Effects in the Relativistic Quantum-Defect-Orbital Theory

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EN
Abstracts
EN
The quantum-defect-orbital method has been reformulated in order to include both relativistic effects and the electron correlation described by a core polarization potential. All quantities appearing in this formulation may be evaluated analytically. A comparison with experimental results demonstrates, on one hand, significance of the relativity-correlation corrections and, on the other, inadequacy of the relativistic quantum-defect-orbital approach when indirect relativistic effects are important, i.e. when atoms contain closed shells of d electrons.
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Contributors
  • Institute of Physics, N. Copernicus University, Grudziądzka 5, 87-100 Toruń, Poland
author
  • Departamento de Química Física, Facultad de Ciencias, Universidad de Valladolid, 47005 Valladolid, Spain
author
  • Institute of Physics, N. Copernicus University, Grudziądzka 5, 87-100 Toruń, Poland
References
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Publication order reference
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bwmeta1.element.bwnjournal-article-appv85z503kz
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