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1993 | 84 | 5 | 903-907

Article title

Spectroscopic Properties of Neodymium Perchlorates in 2-Halogeno Derivatives of Ethanol. Part II

Content

Title variants

Languages of publication

EN

Abstracts

EN
The spectroscopic studies of anhydrous neodymium perchlorate in two series of 2-halogeno derivatives of ethyl alcohol are presented. The changes of intensities of ^{4}I_{9/2} → ^{2}G_{7/2}, ^{4}G_{5/2} hypersensitive transitions are discussed within the framework of Mason's polarizability mechanism. Anomalous dependence of band intensities was found for the 2-fluoro derivatives. The linear relation of oscillator strength vs. solvent polarizability was broken for the 2-bromine and 2-iodine derivatives of ethyl alcohol. The effort was made for explanation of such strange results.

Keywords

EN

Year

Volume

84

Issue

5

Pages

903-907

Physical description

Dates

published
1993-11

Contributors

author
  • Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland
  • Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland

References

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.bwnjournal-article-appv84z510kz
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