Spectroscopic Properties of Neodymium Perchlorates in 2-Halogeno Derivatives of Ethanol. Part II

• Authors: B. Keller , J. Legendziewicz
• Languages of publication: EN

Abstracts

EN

The spectroscopic studies of anhydrous neodymium perchlorate in two series of 2-halogeno derivatives of ethyl alcohol are presented. The changes of intensities of ^{4}I_{9/2} → ^{2}G_{7/2}, ^{4}G_{5/2} hypersensitive transitions are discussed within the framework of Mason's polarizability mechanism. Anomalous dependence of band intensities was found for the 2-fluoro derivatives. The linear relation of oscillator strength vs. solvent polarizability was broken for the 2-bromine and 2-iodine derivatives of ethyl alcohol. The effort was made for explanation of such strange results.

Keywords

EN

78.20.Wc; 78.55.Hx

Discipline

• 78.55.Hx: Other solid inorganic materials

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 1993
• Volume: 84
• Issue: 5
• Pages: 903-907

Dates

published

1993-11

Contributors

author

B. Keller

• Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland

author

J. Legendziewicz

• Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland

Identifiers

DOI

10.12693/APhysPolA.84.903