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1993 | 84 | 2 | 253-258
Article title

Electric Polarization of Onsager Fluids. I. Dipole Polarization. 1. Electric Moments of Free Molecules

Content
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EN
Abstracts
EN
An attempt was made to modify the model Onsager theory. A polarizable molecular dipole enclosed in a spherical cavity is substituted for a rigid one submerged in the polarizable medium which fills the cavity. The local dielectric permittivity of the Heaviside type is replaced for the oscillating, rapidly damping function of the Fresnel integral. The analytical expressions deduced allow to estimate dipoles of free molecules, starting from the results of dielectrometry of polar fluids. The obtained values are as close as possible to the experimental data on a great variety of pure organic liquids.
Keywords
EN
Publisher

Year
Volume
84
Issue
2
Pages
253-258
Physical description
Dates
published
1993-08
received
1993-03-02
(unknown)
1993-04-06
Contributors
author
  • Institute of Chemistry, Pedagogical University, Oleska 48, 45-052 Opole, Poland
author
  • Ukrainian Scientific Center for Water Control, Bakunina 6, Kharkov 310001, Ukraine
author
  • Kharkov University, pl. Nezalezhnosty 4, Kharkov 310077, Ukraine
author
  • Ukrainian Scientific Center for Water Control, Bakunina 6, Kharkov 310001, Ukraine
author
  • Ukrainian Scientific Center for Water Control, Bakunina 6, Kharkov 310001, Ukraine
author
  • Ukrainian Scientific Center for Water Control, Bakunina 6, Kharkov 310001, Ukraine
References
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv84z204kz
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