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1992 | 82 | 3 | 443-449
Article title

Dielectric Study of Dipolar Association in Dihalogenobenzenes

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EN
Abstracts
EN
The nonlinear dielectric effect (NDE) has been studied in o-bromochlorobenzene and m-bromochlorobenzene, and their solutions in benzene. On the basis of NDE results and the values of electric permittivity ε, density d, and refractive index n obtained in this work, the molar polarizabilities: linear ⟨μ^{2}⟩ and nonlinear ⟨μ^{4}⟩ were calculated. Assuming dipolar association of the investigated dihalogenobenzenes molecules to be restricted to dimerization, the Gibbs energy ΔG^{0}_{dim} of the dimerization process as a function of the Onsager field factor f(ε) is determined, which allowed us to draw a conclusion on the structure of associates.
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EN
Publisher

Year
Volume
82
Issue
3
Pages
443-449
Physical description
Dates
published
1992-09
received
1992-06-22
Contributors
author
  • Institute of Physics, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland
References
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv82z308kz
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