Collisional Broadening of the J=7 ⇐ 6 Transition of t-Butyl Cyanide by CH_{3}CN, OCS, CO_{2} and Helium

• Authors: S. Gierszal , J. Galica , E. Miś-Kuźmińska
• Languages of publication: EN

Abstracts

EN

Experimental studies of the broadening of the absorption line J = 6 ⇒ 7 of (CH_{3})_{3}CCN due to collisions with the foreign perturbers He, CO_{2}, OCS, and CH_{3}CN have been carried out. The magnitude of the broadening coefficients reflects the type of interactions occurring in the molecular collisions. It has been concluded that the dipole-dipole and dipole-quadrupole interactions are predominant in the (CH_{3})_{3}CCN admixed with CH_{3}CN and OCS. In the collisions between (CH_{3})_{3}CCN and CO_{2} the dipole-quadrupole interactions are present whereas the He perturbed by (CH_{3})_{3}CCN exhibits dispersive type of interactions.

Keywords

EN

33.70.Jg

Discipline

• 33.70.Jg: Line and band widths, shapes, and shifts

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 1992
• Volume: 81
• Issue: 6
• Pages: 613-617

Dates

published

1992-06

received

1992-04-21

Contributors

author

S. Gierszal

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

author

J. Galica

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

author

E. Miś-Kuźmińska

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

Identifiers

DOI

10.12693/APhysPolA.81.613