Expansion of the Rotational Energy of Diatomic Molecules into a Continued Fraction

• Authors: M. Molski , J. Konarski
• Languages of publication: EN

Abstracts

EN

A new expansion of the rotational energy of diatomic molecules, in the form of a continued fraction has been investigated. The considered formula is applied in calculation of molecular constants and reproduction of rotational spectra of rigid-, semirigid- and van der Waals-type molecules. A physical interpretation of semiempirical expansion parameters is proposed and a connection between the method considered and the Dunham approach is also discussed.

Keywords

EN

33.10.Cs; 33.10.Jz

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 1992
• Volume: 81
• Issue: 4-5
• Pages: 495-501

Dates

published

1992-04

received

1992-01-21

(unknown)

1992-03-30

Contributors

author

M. Molski

• Department of Theoretical Chemistry, Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

author

J. Konarski

• Department of Theoretical Chemistry, Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

Identifiers

DOI

10.12693/APhysPolA.81.495