Expansion of the Rotational Energy of Diatomic Molecules into a Continued Fraction

Molski, M.; Konarski, J.

doi:10.12693/APhysPolA.81.495

Journal

Acta Physica Polonica A

1992 | 81 | 4-5 | 495-501

Article title

Expansion of the Rotational Energy of Diatomic Molecules into a Continued Fraction

Authors

M. Molski , J. Konarski

Content

Full texts:

http://przyrbwn.icm.edu.pl/APP/PDF/81/a081z4p05.pdf [remote]

Title variants

Languages of publication

Abstracts

A new expansion of the rotational energy of diatomic molecules, in the form of a continued fraction has been investigated. The considered formula is applied in calculation of molecular constants and reproduction of rotational spectra of rigid-, semirigid- and van der Waals-type molecules. A physical interpretation of semiempirical expansion parameters is proposed and a connection between the method considered and the Dunham approach is also discussed.

Keywords

33.10.Cs 33.10.Jz

Publisher

Journal

Acta Physica Polonica A

Year

1992

Volume

Issue

4-5

Pages

495-501

Physical description

Dates

published

1992-04

received

1992-01-21

(unknown)

1992-03-30

Contributors

author

M. Molski

Department of Theoretical Chemistry, Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

author

J. Konarski

Department of Theoretical Chemistry, Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland

References

Document Type

Publication order reference

Identifiers

DOI

10.12693/APhysPolA.81.495

YADDA identifier

bwmeta1.element.bwnjournal-article-appv81z405kz