Spin-Allowed Vibronic Transitions in Molecules: Radiative and Non-Radiative Transition Moments by Including Static and Vibronic Spin-Orbit Coupling within the Adiabatic Approximation

• Authors: K. Gustav
• Languages of publication: EN

Abstracts

EN

By making use of the second order Herzberg-Teller approach within the adiabatic approximation including the static and vibronic spin-orbit coupling the vibronic transition moments for spin-allowed radiative and non-radiative processes are derived. The role and the contribution of spin-orbit coupling to both transition moments are illustrated.

Keywords

EN

33.50.-j; 82.50.-m

Discipline

• 33.50.-j: Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)(for energy transfer, see also section 34; for biophysical applications, see 87.64.kv)
• 82.50.-m: Photochemistry(for single molecule photochemistry, see 82.37.Vb)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 1991
• Volume: 80
• Issue: 6
• Pages: 793-800

Dates

published

1991-12

received

1991-06-21

(unknown)

1991-09-06

Contributors

author

K. Gustav

• Friedrich-Schiller University Jena, Institute of Physical Chemistry Philosophenweg 14, D(O)-6900 Jena, Federal Republic of Germany

Identifiers

DOI

10.12693/APhysPolA.80.793