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Number of results
1991 | 79 | 2-3 | 235-238

Article title

Spin-Orbit Coupling in Cr^{3+} Ion in Solid State Materials

Content

Title variants

Languages of publication

EN

Abstracts

EN
In this paper we introduce a new model describing the coupling of ^{2}E and ^{4}T_{2} states of octahedrally coordinated Cr^{3+} ion, which includes spin-orbit and electron-lattice interactions and takes into account the electronic structure of both states. The model is used to calculate doublet lifetime. We have applied this model to the series of Cr^{3+} doped garnets characterized by the varying crystal field parameter 10 Dq and O_{h} symmetry of the Cr site and to the kyanite (Al_{2}O_{3}:SiO_{2}), which is the case of different Cr^{3+} sites in one material, characterized by the relatively large component of the low symmetry crystal field. The agreement with experiment is reasonable.

Keywords

EN

Year

Volume

79

Issue

2-3

Pages

235-238

Physical description

Dates

published
1991-02
received
1990-08-08

Contributors

  • Institute of Physics, N. Copernicus University, Grudziądzka 5, 87-100 Toruń, Poland
author
  • Institute of Physics, N. Copernicus University, Grudziądzka 5, 87-100 Toruń, Poland
author
  • Chemistry Department, Boston University, Boston, USA

References

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.bwnjournal-article-appv79z218kz
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