ORR Electrocatalysis on Cr³⁺, Fe²⁺, Co²⁺-Doped Manganese(IV) Oxides

• Authors: G. Sokolsky , L. Zudina , E. Boldyrev , O. Miroshnikov , N. Gauk , O. Kiporenko
• Languages of publication: EN

Abstracts

EN

The ionic dopant additives have different mechanisms of their influence upon MnO₂ electrocrystallisation process and depending on dopants added the following polymorphs are stabilised: α -MnO₂ (hollandite, I4/m) - NH₄⁺; γ -MnO₂ (ramsdellite, Pbnm) - Co²⁺, Fe²⁺; layered polymorph δ -MnO₂ (birnessite, C2/m) - Cr³⁺. The defect states of intergrowth method in ramsdellite matrix and twinning, OH groups studied by X-ray diffraction and the Fourier transform infrared mtehod, respectively, indicate their high content in case of Fe²⁺ and Co²⁺-doped manganese dioxide. CVA oxygen reduction reaction peaks were established after experiments in alkaline electrolytes and dioxygen (argon, air) atmosphere. Activity of doped samples studied is comparable with other published data. Both doped with Co²⁺ and Fe²⁺ samples display maximal currents and some distinctive features in oxygen reduction reaction.

Keywords

EN

61.66.Fn; 61.72.-y; 85.40.Ry

Discipline

• 61.66.Fn: Inorganic compounds
• 61.72.-y: Defects and impurities in crystals; microstructure(for radiation induced defects, see 61.80.-x; for defects in surfaces, interfaces, and thin films, see 68.35.Dv and 68.55.Ln; see also 85.40.Ry Impurity doping, diffusion, and ion implantation technology; for effects of crystal defects and doping on superconducting transition temperature, see 74.62.Dh)
• 85.40.Ry: Impurity doping, diffusion and ion implantation technology

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2018
• Volume: 133
• Issue: 4
• Pages: 1097-1102

Dates

published

2018-04

Contributors

author

G. Sokolsky

• National University of Food Technologies, Kyiv, Ukraine

author

L. Zudina

• National University of Food Technologies, Kyiv, Ukraine

author

E. Boldyrev

• Institute of General and Inorganic Chemistry of National Academy of Science of Ukraine, Kyiv, Ukraine

author

O. Miroshnikov

• National University of Food Technologies, Kyiv, Ukraine

author

N. Gauk

• National University of Food Technologies, Kyiv, Ukraine

author

O. Kiporenko

• Bogomolets National Medical University, Kyiv, Ukraine

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Identifiers

DOI

10.12693/APhysPolA.131.1097