Catalytic Compositions Based on Chlorides of d Metals and Natural Aluminosilicates for the Low-Temperature Sulfur Dioxide Oxidation with Air Oxygen

• Authors: T. Rakitskaya , T. Kiose , K. Golubchik , G. Dzhiga , A. Ennan , V. Volkova
• Languages of publication: EN

Abstracts

EN

Samples of natural bentonite and clinoptilolite modified with copper(II), iron(III), and palladium(II) were characterized by both X-ray phase and the Fourier transform infrared spectral methods. The activity of monometallic compositions M_{i}L_{j}/S(M = Co(II), Fe(III), and Pd(II); L = NO₃¯, Cl¯, and SO₄²¯; S = N-CLI or N-Bent) in the reaction with sulfur dioxide was found to depend on the nature of both a metal ion and a support. For bimetallic compositions Cu(II)-Fe(III) and Cu(II)-Pd(II) based on the natural aluminosilicates, a certain synergism in the action of metals forming these pairs towards the reaction of sulfur dioxide oxidation with oxygen was determined.

Keywords

EN

61.05.cp; 33.20.Ea; 81.05.Ni

Discipline

• 61.05.cp: X-ray diffraction
• 33.20.Ea: Infrared spectra
• 81.05.Ni: Dispersion-, fiber-, and platelet-reinforced metal-based composites

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2018
• Volume: 133
• Issue: 4
• Pages: 1074-1078

Dates

published

2018-04

Contributors

author

T. Rakitskaya

• Faculty of Chemistry, Odessa I.I. Mechnikov National University, 2, Dvoryanskaya Str., 65082, Odessa, Ukraine

author

T. Kiose

• Faculty of Chemistry, Odessa I.I. Mechnikov National University, 2, Dvoryanskaya Str., 65082, Odessa, Ukraine
• Physico-Chemical Institute of Environment and Human' Protection, Preobrazhenskaya Str., 3, Odessa, 65082, Ukraine

author

K. Golubchik

• Physico-Chemical Institute of Environment and Human' Protection, Preobrazhenskaya Str., 3, Odessa, 65082, Ukraine

author

G. Dzhiga

• Faculty of Chemistry, Odessa I.I. Mechnikov National University, 2, Dvoryanskaya Str., 65082, Odessa, Ukraine

author

A. Ennan

• Physico-Chemical Institute of Environment and Human' Protection, Preobrazhenskaya Str., 3, Odessa, 65082, Ukraine

author

V. Volkova

• Faculty of Chemistry, Odessa I.I. Mechnikov National University, 2, Dvoryanskaya Str., 65082, Odessa, Ukraine

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Identifiers

DOI

10.12693/APhysPolA.131.1074