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2018 | 133 | 4 | 1074-1078
Article title

Catalytic Compositions Based on Chlorides of d Metals and Natural Aluminosilicates for the Low-Temperature Sulfur Dioxide Oxidation with Air Oxygen

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EN
Abstracts
EN
Samples of natural bentonite and clinoptilolite modified with copper(II), iron(III), and palladium(II) were characterized by both X-ray phase and the Fourier transform infrared spectral methods. The activity of monometallic compositions M_{i}L_{j}/S(M = Co(II), Fe(III), and Pd(II); L = NO₃¯, Cl¯, and SO₄²¯; S = N-CLI or N-Bent) in the reaction with sulfur dioxide was found to depend on the nature of both a metal ion and a support. For bimetallic compositions Cu(II)-Fe(III) and Cu(II)-Pd(II) based on the natural aluminosilicates, a certain synergism in the action of metals forming these pairs towards the reaction of sulfur dioxide oxidation with oxygen was determined.
Keywords
EN
Publisher

Year
Volume
133
Issue
4
Pages
1074-1078
Physical description
Dates
published
2018-04
Contributors
author
  • Faculty of Chemistry, Odessa I.I. Mechnikov National University, 2, Dvoryanskaya Str., 65082, Odessa, Ukraine
author
  • Faculty of Chemistry, Odessa I.I. Mechnikov National University, 2, Dvoryanskaya Str., 65082, Odessa, Ukraine
  • Physico-Chemical Institute of Environment and Human' Protection, Preobrazhenskaya Str., 3, Odessa, 65082, Ukraine
author
  • Physico-Chemical Institute of Environment and Human' Protection, Preobrazhenskaya Str., 3, Odessa, 65082, Ukraine
author
  • Faculty of Chemistry, Odessa I.I. Mechnikov National University, 2, Dvoryanskaya Str., 65082, Odessa, Ukraine
author
  • Physico-Chemical Institute of Environment and Human' Protection, Preobrazhenskaya Str., 3, Odessa, 65082, Ukraine
author
  • Faculty of Chemistry, Odessa I.I. Mechnikov National University, 2, Dvoryanskaya Str., 65082, Odessa, Ukraine
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv133n4p74kz
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