Interaction of the Components in the BaO-Tb₂O_{3+δ}-CuO and Related Systems

• Authors: O. Zaremba , R. Gladyshevskii
• Languages of publication: EN

Abstracts

EN

The isothermal section of the phase diagram of the BaO-Tb₂O_{3+δ}-CuO system at 1173 K was constructed based on X-ray powder diffraction data. The existence of the compounds BaTbO₃ (SrZrO₃ structure type, I4/mcm, a = 0.6034(1), c = 0.8576(1) nm) and Ba₄₄Cu₄₅O₉₀ (own structure type, Im-3m, a =1.8266(3) nm) was confirmed in the binary BaO-Tb₂O₃ and BaO-CuO systems, respectively, but no ternary oxides were found. The investigation of samples with nominal composition A_{0.5}Tb_{0.5}TO₃ (A = Ca, Sr or Ba, T = Ni or Zn) showed the presence of phases from the corresponding binary systems, or unreacted reagents.

Keywords

EN

61.66.Fn

Discipline

• 61.66.Fn: Inorganic compounds

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2018
• Volume: 133
• Issue: 4
• Pages: 1024-1026

Dates

published

2018-04

Contributors

author

O. Zaremba

• Ivan Franko National University of Lviv, Kyryla i Mefodiya Str. 6, UA-79005 Lviv, Ukraine

author

R. Gladyshevskii

• Ivan Franko National University of Lviv, Kyryla i Mefodiya Str. 6, UA-79005 Lviv, Ukraine

References

• [1] Pearson's Crystal Data - Crystal Structure Database for Inorganic Compounds, Eds. P. Villars, K. Cenzual, ASM International, Materials Park (OH), USA, release 2014/15
• [2] D.B. Wiles, A. Sakthivel, R.A. Young, Program DBWS3.2 for Rietveld analysis of X-ray and neutron powder diffraction patterns, School of Physics, Georgia Institute of Technology, Atlanta (GA), USA 1998
• [3] H. Ouchi, Ferroelectrics 95, 215 (1989) , doi: 10.1080/00150198908245207
• [4] C. Gao, H. Wang, T.Z. Cheng, Y. Liu, W. Liu, Y. Qian, Z. Chen, Solid State Commun. 70, 631 (1989) , doi: 10.1016/0038-1098(89)90363-3

Identifiers

DOI

10.12693/APhysPolA.131.1024