Investigation of Co Ions Diffusion in Gd₃Ga₅O₁₂ Single Crystals

• Authors: D. Sugak , I. Syvorotka , U. Yakhnevych , O. Buryy , M. Vakiv , S. Ubizskii , D. Włodarczyk , Ya. Zhydachevskyy , A. Pieniążek , R. Jakiela , A. Suchocki
• Languages of publication: EN

Abstracts

EN

Spatial changes of properties of Gd₃Ga₅O₁₂ (GGG) single crystals caused by diffusion of cobalt ions during high-temperature annealing (1200°C, 24 h) in Co₃O₄ powder are investigated. The registration of these changes was carried out by optical spectrophotometry, microscopy and micro-Raman scattering methods. Changes in structure of near-surface layers of the crystal were investigated by X-ray diffraction technique. It was shown that the additional absorption induced by annealing is related to intra-center optical transitions in Co²⁺ ions, which occupy tetrahedral positions in the garnet structure at the distances of 250-500 μm from the crystal surface. The dependence of induced absorption with depth has got a non-monotonous character with a maximum at 400 μm. A comparison of the results obtained by different methods allows to suppose that the thermal treatment of GGG in the presence of cobalt ions leads to formation of the structurally and chemically non-uniform layer with a width about 500 μm.

Keywords

EN

66.30.-h; 78.20.-e

Discipline

• 78.20.-e: Optical properties of bulk materials and thin films(for optical properties related to materials treatment, see 81.40.Tv; for optical materials, see 42.70-a; for optical properties of superconductors, see 74.25.Gz; for optical properties of rocks and minerals, see 91.60.Mk; for optical properties of specific thin films, see 78.66.-w)
• 66.30.-h: Diffusion in solids(for surface and interface diffusion, see 68.35.Fx)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2018
• Volume: 133
• Issue: 4
• Pages: 959-964

Dates

published

2018-04

Contributors

author

D. Sugak

• Lviv Polytechnic National University, Lviv, Ukraine
• Scientific Research Company "Electron-Carat", Lviv, Ukraine

author

I. Syvorotka

• Lviv Polytechnic National University, Lviv, Ukraine
• Scientific Research Company "Electron-Carat", Lviv, Ukraine

author

U. Yakhnevych

• Lviv Polytechnic National University, Lviv, Ukraine

author

O. Buryy

• Lviv Polytechnic National University, Lviv, Ukraine

author

M. Vakiv

• Lviv Polytechnic National University, Lviv, Ukraine
• Scientific Research Company "Electron-Carat", Lviv, Ukraine

author

S. Ubizskii

• Lviv Polytechnic National University, Lviv, Ukraine

author

D. Włodarczyk

• Institute of Physics, Polish Academy of Sciences, Warsaw, Poland

author

Ya. Zhydachevskyy

• Lviv Polytechnic National University, Lviv, Ukraine
• Institute of Physics, Polish Academy of Sciences, Warsaw, Poland

author

A. Pieniążek

• Institute of Physics, Polish Academy of Sciences, Warsaw, Poland

author

R. Jakiela

• Institute of Physics, Polish Academy of Sciences, Warsaw, Poland

author

A. Suchocki

• Institute of Physics, Polish Academy of Sciences, Warsaw, Poland
• Institute of Physics, Kazimierz Wielki University, Bydgoszcz, Poland

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Identifiers

DOI

10.12693/APhysPolA.131.959