Luminescent Spectroscopy of the Yb³⁺ Ions in the PbWO₄ Crystal

• Authors: O. Chukova , S. Nedilko
• Languages of publication: EN

Abstracts

EN

Luminescent properties of the PbWO₄ crystals undoped and doped with the Yb³⁺ ions were studied. Emission spectra of the crystals consist of broadband matrix emission in 350-750 nm spectral range and narrow spectral lines caused by inner electron transitions in the impurity Yb³⁺ ions in 920-1040 nm spectral range. Analysis of the linear spectra has shown that Yb³⁺ ions form two types of emission centres. Structures of these centers are discussed taking into account possibility of the impurity ions incorporation in different positions (Pb and W sites) in the crystal lattice. Effects of the Yb³⁺ impurities on matrix emission were studied. Transfer of excitation energy from matrix to the Yb³⁺ decreases intensity of the red band of matrix emission. The Yb³⁺ impurities also increase intensity of the blue band by formation of additional Yb³⁺-induced channel of excitation of this band. The described effects of Yb³⁺ doping on properties of matrix emission are caused by the Yb³⁺ ions arranged in Pb positions.

Keywords

EN

61.72.Ji; 78.55.Hx

Discipline

• 78.55.Hx: Other solid inorganic materials

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2018
• Volume: 133
• Issue: 4
• Pages: 918-922

Dates

published

2018-04

Contributors

author

O. Chukova

• Physics Faculty, National Taras Shevchenko University of Kyiv, 4-b, acad. Hlushkov Ave., 03680, Kyiv, Ukraine

author

S. Nedilko

• Physics Faculty, National Taras Shevchenko University of Kyiv, 4-b, acad. Hlushkov Ave., 03680, Kyiv, Ukraine

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Identifiers

DOI

10.12693/APhysPolA.131.918