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2018 | 133 | 4 | 918-922
Article title

Luminescent Spectroscopy of the Yb³⁺ Ions in the PbWO₄ Crystal

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EN
Abstracts
EN
Luminescent properties of the PbWO₄ crystals undoped and doped with the Yb³⁺ ions were studied. Emission spectra of the crystals consist of broadband matrix emission in 350-750 nm spectral range and narrow spectral lines caused by inner electron transitions in the impurity Yb³⁺ ions in 920-1040 nm spectral range. Analysis of the linear spectra has shown that Yb³⁺ ions form two types of emission centres. Structures of these centers are discussed taking into account possibility of the impurity ions incorporation in different positions (Pb and W sites) in the crystal lattice. Effects of the Yb³⁺ impurities on matrix emission were studied. Transfer of excitation energy from matrix to the Yb³⁺ decreases intensity of the red band of matrix emission. The Yb³⁺ impurities also increase intensity of the blue band by formation of additional Yb³⁺-induced channel of excitation of this band. The described effects of Yb³⁺ doping on properties of matrix emission are caused by the Yb³⁺ ions arranged in Pb positions.
Keywords
EN
Publisher

Year
Volume
133
Issue
4
Pages
918-922
Physical description
Dates
published
2018-04
Contributors
author
  • Physics Faculty, National Taras Shevchenko University of Kyiv, 4-b, acad. Hlushkov Ave., 03680, Kyiv, Ukraine
author
  • Physics Faculty, National Taras Shevchenko University of Kyiv, 4-b, acad. Hlushkov Ave., 03680, Kyiv, Ukraine
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv133n4p37kz
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