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2018 | 133 | 4 | 802-805
Article title

Synthesis and Structure Characterisation of Micro-and Nanocrystalline Powders of Dy_{1-x}R_xFeO₃ (R = La, Pr, Nd, Sm, Gd)

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EN
Abstracts
EN
This work deals with the study of the phase and crystal structure behaviour of new micro- and nanocrystalline ferrites Dy_{1-x}R_xFeO₃ obtained by solid state reactions (R = La, Pr) and sol-gel citrate (R = Nd, Sm, Gd) techniques. It was established that all synthesized samples adopt orthorhombic perovskite structure isotypic with GdFeO₃. Unit cell dimensions and atomic coordinates of the mixed rare earth ferrites derived by full profile Rietveld refinement technique agree well with the data of the "pure" DyFeO₃ and RFeO₃ compounds, thus proving formation of continuous solid solutions Dy_{1-x}R_xFeO₃ in the DyFeO₃-RFeO₃ systems (R = La, Pr, Nd, Sm, Gd). Peculiarity of the Dy_{1-x}La_xFeO₃ series is the lattice parameters crossover and formation of dimensionally tetragonal structure at x ≈0.97.
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EN
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Year
Volume
133
Issue
4
Pages
802-805
Physical description
Dates
published
2018-04
Contributors
author
  • Semiconductor Electronics Department of Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine
author
  • Department of Chemical Technology of Silicates of Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine
author
  • Department of Applied Physics and Nanomaterials Science of Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine
  • Semiconductor Electronics Department of Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine
  • Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL-02668 Warsaw, Poland
author
  • Department of Chemical Technology of Silicates of Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine
  • Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL-02668 Warsaw, Poland
author
  • Semiconductor Electronics Department of Lviv Polytechnic National University, 12 Bandera Str., 79013 Lviv, Ukraine
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv133n4p11kz
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