Presence of Oxygen in Ti-Al-C MAX Phases-Based Materials and their Stability in Oxidizing Environment at Elevated Temperatures

• Authors: T. Prikhna , O. Ostash , V. Sverdun , M. Karpets , T. Zimych , A. Ivasyshin , T. Cabioc'h , P. Chartier , S. Dub , L. Javorska , V. Podgurska , P. Figel , J. Cyboroń , V. Moshchil , V. Kovylaev , S. Ponomaryov , V. Romaka , T. Serbenyuk , A. Starostina
• Languages of publication: EN

Abstracts

EN

The Ti₃AlC₂-, (Ti,Nb)₃AlC₂- and Ti₂AlC-based materials turned out to be more resistant than Crofer JDA steel in oxidizing atmosphere as 1000 h long tests at 600°C have shown. But the amounts of oxygen absorbed by the materials during testing were different. The Ti₂AlC-based material demonstrated the lowest oxygen uptake, (Ti,Nb)₃AlC₂-based absorbed a somewhat higher amount and the highest amount was absorbed by Ti₃AlC₂-based material. Scanning electron microscopy and the Auger study witnessed that amounts of oxygen in the MAX phases before the exposure in air were as well different: the approximate stoichiometries of the matrix phases of materials were Ti_{3.1-3.2}AlC_{2-2.2}, Ti_{1.9-4}Nb_{0.06-0.1}AlC_{1.6-2.2}O_{0.1-1.2} and Ti_{2.3-3.6}AlC_{1-1.9}O_{0.2-0.6}, respectively. The higher amount of oxygen present in the MAX phase structures may be the reason for higher resistance to oxidation during long-term heating in air at elevated temperature. The studied materials demonstrated high stabilities in hydrogen atmosphere as well. The bending strength of the Ti₃AlC₂- and (Ti,Nb)₃AlC₂-based materials after keeping at 600°C in air and hydrogen increased by 10-15%, but the highest absolute value of bending strength before and after being kept in air and hydrogen demonstrated the Ti₂AlC-based material (about 590 MPa).

Keywords

EN

Ti-Al-C MAX phases; high- temperature resistance in air and hydrogen; hot pressing; bending strength

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2018
• Volume: 133
• Issue: 4
• Pages: 789-793

Dates

published

2018-04

Contributors

author

T. Prikhna

• Institute for Superhard Materials of the National Academy of Sciences of Ukraine, 2 Avtozavodskaya Str., Kiev, 04074, Ukraine

author

O. Ostash

• Karpenko Physical-Mechanical Institute of the National Academy of Sciences of Ukraine, 5, Naukova Str. Lviv, 79060, Ukraine

author

V. Sverdun

• Institute for Superhard Materials of the National Academy of Sciences of Ukraine, 2 Avtozavodskaya Str., Kiev, 04074, Ukraine

author

M. Karpets

• Institute for Superhard Materials of the National Academy of Sciences of Ukraine, 2 Avtozavodskaya Str., Kiev, 04074, Ukraine

author

T. Zimych

• Institute for Superhard Materials of the National Academy of Sciences of Ukraine, 2 Avtozavodskaya Str., Kiev, 04074, Ukraine

author

A. Ivasyshin

• Karpenko Physical-Mechanical Institute of the National Academy of Sciences of Ukraine, 5, Naukova Str. Lviv, 79060, Ukraine

author

T. Cabioc'h

• Université de Poitiers, CNRS/Laboratoire PHYMAT, UMR 6630 CNRS Université de Poitiers SP2MI, BP 30179, F-86962 Chasseneuil Futuroscope Cedex, France

author

P. Chartier

• Université de Poitiers, CNRS/Laboratoire PHYMAT, UMR 6630 CNRS Université de Poitiers SP2MI, BP 30179, F-86962 Chasseneuil Futuroscope Cedex, France

author

S. Dub

• Institute for Superhard Materials of the National Academy of Sciences of Ukraine, 2 Avtozavodskaya Str., Kiev, 04074, Ukraine

author

L. Javorska

• The Institute of Advanced Manufacturing Technology, Wroclawska 37A, 30-011 Krakow, Poland

author

V. Podgurska

• Karpenko Physical-Mechanical Institute of the National Academy of Sciences of Ukraine, 5, Naukova Str. Lviv, 79060, Ukraine

author

P. Figel

• The Institute of Advanced Manufacturing Technology, Wroclawska 37A, 30-011 Krakow, Poland

author

J. Cyboroń

• The Institute of Advanced Manufacturing Technology, Wroclawska 37A, 30-011 Krakow, Poland

author

V. Moshchil

• Institute for Superhard Materials of the National Academy of Sciences of Ukraine, 2 Avtozavodskaya Str., Kiev, 04074, Ukraine

author

V. Kovylaev

• EDL "Proton 21", 48a, Chernovola Str., Kiev's region 08132, Vishnevoe, Ukraine

author

S. Ponomaryov

• EDL "Proton 21", 48a, Chernovola Str., Kiev's region 08132, Vishnevoe, Ukraine

author

V. Romaka

• Lviv Polytechnic National University, 12 Bandera Str., Lviv, 79013, Ukraine

author

T. Serbenyuk

• Institute for Superhard Materials of the National Academy of Sciences of Ukraine, 2 Avtozavodskaya Str., Kiev, 04074, Ukraine

author

A. Starostina

• Institute for Superhard Materials of the National Academy of Sciences of Ukraine, 2 Avtozavodskaya Str., Kiev, 04074, Ukraine

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Identifiers

DOI

10.12693/APhysPolA.131.789