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2018 | 133 | 3 | 398-400

Article title

Physical Properties Study of the CeOsGa₄ Compound

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EN

Abstracts

EN
A polycrystalline sample of CeOsGa₄ was prepared by arc-melting stoichiometric quantities of high purity elements of 4N and greater, in an arc furnace. The data was confirmed to crystallize in an orthorhombic structure, with a space group Pmma (Number 51). Measurements of the magnetic susceptibility showed a distinct anomaly around T_{o} = 3.8 K, while the high temperature data (above 100 K) obeys Curie-Weiss law. The calculated effective moment of 2.44 μ_{B}, was obtained, which was a bit less than the theoretical moment for a Ce³⁺ ion of 2.54 μ_{B}. Magnetization data at T=2 K depicts that CeOsGa₄ does not saturate up to applied magnetic field of 7 T, while the data measured at 9 K indicates that the compound is purely paramagnetic at that temperature. The low temperature specific heat data is characterized by an anomaly at T_{o} = 3.8 K confirming the χ(T) data. Electrical resistivity shows a metallic behaviour at high temperatures with a deviation at low temperatures, signalling the cooperative behaviour which results to ordering. In this work we present the initial studies of the physical properties measurements performed on this compound.

Keywords

EN

Contributors

author
  • Highly Correlated Matter Research Group, Department of Physics, University of Johannesburg, P.O. Box 524, Auckland Park 2006, South Africa
author
  • Highly Correlated Matter Research Group, Department of Physics, University of Johannesburg, P.O. Box 524, Auckland Park 2006, South Africa

References

  • [1] Yu.N. Grin', R.E. Gladyshevskii, O.M. Sichevich, V.E. Zavodnik, Ya.P. Yarmolyuk, I.V. Rozhdestvenskaya, Sov. Phys. Crystallogr. 29, 528 (1984)
  • [2] Yu.N. Grin', P. Rogl, Izv. Akad. Nauk SSSR, Neorg. Mater. 25, 593 (1989)
  • [3] M. Schlüter, W. Jeitschko, Inorg. Chem. 40, 6362 (2001), doi: 10.1021/ic010629i
  • [4] M. Schlüter, W. Jeitschko, Z. Anorg. Allg. Chem. 626, 2217 (2000), doi: 10.1002/1521-3749(200010)626:10%3C2217::AID-ZAAC2217%3E3.0.CO;2-B
  • [5] M. Schlüter, W. Jeitschko, Z. Anorg. Allg. Chem. 628, 1505 (2002), doi: 10.1002/1521-3749(200207)628:7%3C1505::AID-ZAAC1505%3E3.0.CO;2-3

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.bwnjournal-article-appv133n3p018kz
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