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2017 | 132 | 5 | 1552-1555
Article title

Positron Annihilation Studies of the Free Volumes in Nylon12/PVA Films Treated by Supercritical Carbon Dioxide

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EN
Abstracts
EN
Free volume variations of Nylon12/Polyvinyl alcohol (Nylon12/PVA) blends treated in supercritical carbon dioxide (ScCO₂) were investigated using positron annihilation lifetime spectroscopy. It is found that o-Ps lifetime τ₃ and the corresponding intensity I₃ in Nylon12/PVA decrease with increase of the PVA content. Being treated in ScCO₂ at 50°C and 20 MPa for 1 h, the free volume holes in Nylon12/PVA blends expand to different extents depending on the weight ratio of PVA. After releasing of CO₂, the free volume size decreases as a function of the elapsed time due to the molecular relaxation, and the relaxation time constant depends on the content of PVA in the blends.
Year
Volume
132
Issue
5
Pages
1552-1555
Physical description
Dates
published
2017-11
References
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.bwnjournal-article-appv132n5p25kz
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