Poly(2-acrylamido-2-methyl-1-propane sulfonic acid-co-1-vinyl-2-pyrrolidone) Hydrogel and its use in the Removal of Cd(II), Pb(II) and Cu(II)

• Authors: S. Çavuş , E. Çakal
• Languages of publication: EN

Abstracts

EN

Poly(2-acrylamido-2-methyl-1-propanesulfonic acid-co-1-vinyl-2-pyrrolidone), P(AMPS-co-VP), hydrogel was prepared by free radical cross-linking polymerization method. Prepared hydrogel was used in the competitive removal of Cd(II), Pb(II) and Cu(II) ions from aqueous solution. The characterization of P(AMPS-co-VP) before and after sorption was carried out by the Fourier transform infrared spectroscopy, thermogravimetric analysis and scanning electron microscopy. Atomic absorption spectrometer was used to found the concentration of metal ions in the aqueous solution. The selectivity of P(AMPS-co-VP) was as follows: Cd(II)>Pb(II)>Cu(II). Kinetic study showed that competitive removal of heavy metal ions on poly(AMPS-co-VP) was in accordance with a pseudo-second-order model.

Keywords

EN

sorption; heavy metal ions; hydrogels; sulfonic acid

• Journal: Acta Physica Polonica A
• Year: 2017
• Volume: 132
• Issue: 3
• Pages: 505-508

Dates

published

2017-09

Contributors

author

S. Çavuş

• Istanbul University, Faculty of Engineering, Department of Chemical Engineering, Istanbul, Turkey

author

E. Çakal

• Istanbul University, Faculty of Engineering, Department of Chemical Engineering, Istanbul, Turkey

References

• [1] A. Petrovič, M. Simonič, Int. J. Environm. Sci. Technol. 13, 1761 (2016), doi: 10.1007/S13762-016-1015-2
• [2] M. El Tokhi, B.M. Amin, S. Alaabed, Acta. Phys. Pol. A 130, 138 (2016), doi: 10.12693/APhysPolA.130.138
• [3] U. Yildiz, Ö.F. Kemik, B. Hazer, J. Hazard. Mater. 183, 521 (2010), doi: 10.1016/j.jhazmat.2010.07.055
• [4] I. Clara, R. Lavanya, N. Natchimuthu, J. Macromol. Sci. A Pure Appl. Chem. 53, 492 (2016), doi: 10.1080/10601325.2016.1189282
• [5] F. Akti, F. Boran, Acta. Phys. Pol. A 130, 147 (2016), doi: 10.12693/APhysPolA.130.147
• [6] A.M. Atta, H.S. Ismail, A.M. Elsaaed, J. Appl. Polym. Sci. 123, 2500 (2012), doi: 10.1002/app.34798
• [7] H. Valle, J. Sanchez, B.L. Rivas, J. Appl. Polym. Sci. 132, 41272 (2015), doi: 10.1002/app.41272
• [8] J. Guo, L. Li, Y. Ti, J. Zhu, Express Polym. Lett. 1, 166 (2007), doi: 10.3144/expresspolymlett.2007.26
• [9] S. Çavuş, G. Yaşar, Y. Kaya, Z.B. Gönder, G. Gürdağ, İ. Vergili, Process Safety Environm. Protect. 103, 227 (2016), doi: 10.1016/j.psep.2016.07.011
• [10] P.V. Dadhaniya, M.P. Patel, R.G. Patel, J. Macromol. Sci. A Pure Appl. Chem. 44, 769 (2007), doi: 10.1080/10601320701353694
• [11] H. Chen, A. Wang, J. Hazard. Mater. 165, 223 (2009), doi: 10.1016/j.jhazmat.2008.09.097
• [12] Y.S. Ho, G. McKay, Process Biochem. 34, 451 (1999), doi: 10.1016/S0032-9592(98)00112-5
• [13] M.H. Kalavathy, T. Karthikeyan, S. Rajgopal, L.R. Miranda, J. Coll. Interf. Sci. 292, 354 (2005), doi: 10.1016/j.jcis.2005.05.087
• [14] Y.-S. Ho, J. Hazard. Mater. B 136, 681 (2006), doi: 10.1016/j.jhazmat.2005.12.043
• [15] B. Tugrul, S. Erentürk, S. Haciyakupoglu, N. Karatepe, N. Altinsoy, N. Baydogan, F. Baytas, B. Büyük, E. Demir, S. Gedik, Acta. Phys. Pol. A 128, B-180 (2015), doi: 10.12693/APhysPolA.128.B-180
• [16] J. Qiao, T. Hamaya, T. Okada, Polymer 46, 10809 (2005), doi: 10.1016/j.polymer.2005.09.007
• [17] F. Ge, M-M. Li, H. Ye, B.-X. Zhao, J. Hazard. Mater. 211-212, 366 (2012), doi: 10.1016/j.jhazmat.2011.12.013
• [18] Y.S. Ho, G. McKay, Water Res. 34, 735 (2000), doi: 10.1016/S0043-1354(99)00232-8

Identifiers

DOI

10.12693/APhysPolA.132.505