Magnetic Study of Phases in FeVO₄-Co₃V₂O₈ System

• Authors: N. Guskos , G. Zolnierkiewicz , M. Pilarska , J. Typek , A. Blonska-Tabero , C. Aidinis
• Languages of publication: EN

Abstracts

EN

Magnetic properties of four nFeVO₄/(1-n)Co₃V₂O₈ samples obtained in reactions between FeVO₄ and Co₃V₂O₈ (n = 0.96, 0.86, 0.84 and 0.83, samples designated S1, S3, S4, S5, respectively) have been investigated by DC magnetisation in field cooling and zero-field-cooling modes and EPR. DC magnetic susceptibility showed paramagnetic behavior of all samples in high-temperature range (T > 20 K) and transition to antiferromagnetic state at 16-18 K (depending on sample iron content). Additional magnetic freezing at 8 K was registered for S3-S5 samples containing larger amount of cobalt. The Curie-Weiss law in 100-300 K temperature range indicates that Co²⁺ is in the high-spin state (S = 3/2). From the parameters of the hysteresis loop observed for the samples it was calculated that 0.58% of all magnetic (Fe³⁺, Co²⁺) ions were involved in the ferromagnetic states. EPR spectra of the samples were recorded in high temperature range (T > 90 K). The temperature dependence of the spectral parameters (resonance field, linewidth, integrated intensity) suggested the Fe³⁺ high-spin ions coupled by antiferromagnetic interaction and clusters of ions play major role in EPR spectra.

Keywords

EN

75.40.Cx; 75.50.Ee; 76.30.Fc

Discipline

• 75.50.Ee: Antiferromagnetics
• 75.40.Cx: Static properties (order parameter, static susceptibility, heat capacities, critical exponents, etc.)
• 76.30.Fc: Iron group (3d) ions and impurities (Ti-Cu)

• Journal: Acta Physica Polonica A
• Year: 2017
• Volume: 132
• Issue: 1
• Pages: 24-30

Dates

published

2017-07

Contributors

author

N. Guskos

• Institute of Physics, West Pomeranian University of Technology, Szczecin, al. Piastów 48, 70-311 Szczecin, Poland

author

G. Zolnierkiewicz

• Institute of Physics, West Pomeranian University of Technology, Szczecin, al. Piastów 48, 70-311 Szczecin, Poland

author

M. Pilarska

• Institute of Physics, West Pomeranian University of Technology, Szczecin, al. Piastów 48, 70-311 Szczecin, Poland

author

J. Typek

• Institute of Physics, West Pomeranian University of Technology, Szczecin, al. Piastów 48, 70-311 Szczecin, Poland

author

A. Blonska-Tabero

• Department of Inorganic and Analytical Chemistry, Faculty of Technology and Chemical Engineering, West Pomeranian University of Technology, Szczecin, al. Piastów 42, 70-065 Szczecin, Poland

author

C. Aidinis

• Department of Electrical Engineering, Ajman University of Science and Technology, P.O. Box 346, Ajman, UAE

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Identifiers

DOI

10.12693/APhysPolA.132.24