Preferences help
enabled [disable] Abstract
Number of results
2017 | 132 | 1 | 24-30
Article title

Magnetic Study of Phases in FeVO₄-Co₃V₂O₈ System

Title variants
Languages of publication
Magnetic properties of four nFeVO₄/(1-n)Co₃V₂O₈ samples obtained in reactions between FeVO₄ and Co₃V₂O₈ (n = 0.96, 0.86, 0.84 and 0.83, samples designated S1, S3, S4, S5, respectively) have been investigated by DC magnetisation in field cooling and zero-field-cooling modes and EPR. DC magnetic susceptibility showed paramagnetic behavior of all samples in high-temperature range (T > 20 K) and transition to antiferromagnetic state at 16-18 K (depending on sample iron content). Additional magnetic freezing at 8 K was registered for S3-S5 samples containing larger amount of cobalt. The Curie-Weiss law in 100-300 K temperature range indicates that Co²⁺ is in the high-spin state (S = 3/2). From the parameters of the hysteresis loop observed for the samples it was calculated that 0.58% of all magnetic (Fe³⁺, Co²⁺) ions were involved in the ferromagnetic states. EPR spectra of the samples were recorded in high temperature range (T > 90 K). The temperature dependence of the spectral parameters (resonance field, linewidth, integrated intensity) suggested the Fe³⁺ high-spin ions coupled by antiferromagnetic interaction and clusters of ions play major role in EPR spectra.
  • Institute of Physics, West Pomeranian University of Technology, Szczecin, al. Piastów 48, 70-311 Szczecin, Poland
  • Institute of Physics, West Pomeranian University of Technology, Szczecin, al. Piastów 48, 70-311 Szczecin, Poland
  • Institute of Physics, West Pomeranian University of Technology, Szczecin, al. Piastów 48, 70-311 Szczecin, Poland
  • Institute of Physics, West Pomeranian University of Technology, Szczecin, al. Piastów 48, 70-311 Szczecin, Poland
  • Department of Inorganic and Analytical Chemistry, Faculty of Technology and Chemical Engineering, West Pomeranian University of Technology, Szczecin, al. Piastów 42, 70-065 Szczecin, Poland
  • Department of Electrical Engineering, Ajman University of Science and Technology, P.O. Box 346, Ajman, UAE
  • [1] N. Guskos, G. Zolnierkiewicz, J. Typek, A. Blonska-Tabero, Physica B 406, 2163 (2011), doi: 10.1016/j.physb.2011.03.023
  • [2] N. Guskos, G. Zolnierkiewicz, J. Typek, R. Szymczak, A. Guskos, P. Berczynski, A. Blonska-Tabero, Mater. Sci.-Pol. 31, 601 (2013), doi: 10.2478/s13536-013-0145-1
  • [3] N. Guskos, V. Likodimos, S. Glenis, G. Zolnierkiewicz, J. Typek, R. Szymczak, A. Blonska-Tabero, J. Appl. Phys. 101, 103922 (2007), doi: 10.1063/1.2740329
  • [4] G. Zolnierkiewicz, N. Guskos, J. Typek, E.A. Anagnostakis, A. Blonska-Tabero, M. Bosacka, J. Alloys Comp. 471, 28 (2009), doi: 10.1016/j.jallcom.2008.03.109
  • [5] N. Guskos, H. Ohta, G. Zolnierkiewicz, S. Okubo, W.-M. Zhang, J. Typek, C. Rudowicz, R. Szymczak, M. Bosacka, T. Nakamura, J. Non-Cryst. Solids 355, 1419 (2009), doi: 10.1016/j.jnoncrysol.2009.05.031
  • [6] J. Typek, G. Zolnierkiewicz, N. Guskos, R. Szymczak, A. Blonska-Tabero, Rev. Adv. Mater. Sci. 23, 207 (2010)
  • [7] J. Typek, G. Zolnierkiewicz, M. Bobrowska, N. Guskos, A. Blonska-Tabero, Solid State Sci. 34, 31 (2014), doi: 10.1016/j.solidstatesciences.2014.05.010
  • [8] A. Bezkrovnyi, N. Guskos, J. Typek, N.Yu. Ryabova, M. Bosacka, A. Blonska-Tabero, M. Kurzawa, I. Rychlowska-Himmel, G. Zolnierkiewicz, Mater. Sci.-Pol. 23, 883 (2005)
  • [9] N. Guskos, A. Bezkrovnyi, J. Typek, N.Yu. Ryabova, A. Blonska-Tabero, M. Kurzawa, M. Maryniak, J. Alloys Comp. 391, 20 (2005), doi: 10.1016/j.jallcom.2004.08.067
  • [10] A. Blonska-Tabero, M. Kurzawa, J. Therm. Anal. Calorim. 88, 33 (2007), doi: 10.1007/s10973-006-8046-8
  • [11] X. Wang, D.A. Vander Griend, C.L. Stern, K.R. Poeppelmeir, Inorg. Chem. 39, 136 (2000), doi: 10.1021/ic9909274
  • [12] B. Bojanowski, S. Kaczmarek, Mater. Sci.-Pol. 32, 188 (2014), doi: 10.2478/s13536-013-0192-7
  • [13] Y. Chen, J.W. Lynn, Q. Huang, F.M. Woodward, T. Yildirim, G. Lawes, A.P. Ramirez, N. Rogado, R.J. Cava, A. Aharony, O. Entin-Wohlman, A.B. Harris, Phys. Rev. B 74, 014430 (2006), doi: 10.1103/PhysRevB.74.014430
  • [14] H. Martinho, N.O. Moreno, J.A. Sanjurjo, C. Rettori, A.J. García-Adeva, D.L. Huber, S.B. Oseroff, W. Ratcliff II, S.-W. Cheong, P.G. Pagliuso, J.L. Sarrao, G. B. Martins, Phys. Rev. B 64, 024408 (2001), doi: 10.1103/PhysRevB.64.024408
  • [15] J. Lin, P. Tong, D. Cui, C. Yang, J. Yang, S. Lin, B. Wang, W. Tong, L. Zhang, Y. Zou, Y. Sun, Sci. Rep. 5, 7933 (2015), doi: 10.1038/srep07933
  • [16] R.J.D. Tilley, Perovskites: Structure-Property Relationships, Wiley, Chichester 2016, doi: 10.1002/9781118935651
  • [17] E.I. Kondorskii, O.S. Galkina, L.V. Lazareva, JETP Lett. 30, 656 (1979)
  • [18] L. Sorace, D. Gatteschi, in: Inorganic and Bio-Inorganic Chemistry, Vol. 1, Ed. I. Bertini, Eolss Publ., Oxford 2009, p. 199
  • [19] S.V. Demishev, A.V. Semeno, N.E. Sluchanko, N.A. Samarin, A.A. Pronin, Y. Inogaki, S. Okubo, H. Ohta, Y. Oshima, L.I. Leonyuk, Phys. Solid State 46, 2238 (2004), doi: 10.1134/1.1841388
Document Type
Publication order reference
YADDA identifier
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.